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Thermal conductivity and dynamic heat capacity across the metal-insulator transition in thin film VO2
Abstract
The thermal properties of VO2 thin films, 90–440 nm thick, are measured by time-domain thermoreflectance (TDTR) across the metal-insulator transition (MIT). The thermal conductivity increases by as much as 60% in the metallic phase; this increase in conductivity is in good agreement with the expected electronic contribution to the thermal conductivity. For relatively thick layers, TDTR data are sensitive to the dynamic heat capacity and show a pronounced peak near the MIT temperature created by a contribution to the enthalpy from periodic transformations at the 10 MHz frequency of the thermal waves used in the experiment. The dynamic heat capacity increases as the amplitude ΔT of the thermal waves becomes comparable to the width of the MIT and reaches ≈30% of the bulk latent heat for ΔT≈1.6 K.
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“Over the past two decades, ultrafast laser-based time-domain thermoreflectance (TDTR) has emerged and evolved as a reliable, powerful, and versatile technique to measure the thermal properties of a wide range of bulk and thin film materials and their interfaces.”
From Tutorial: Time-domain thermoreflectance (TDTR) for thermal property characterization of bulk and thin film materials (2018) · cites this paper as [28]
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Cites
Analysis of heat flow in layered structures for time-domain thermoreflectance
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Electronic Properties of V O2 near the Semiconductor-Metal Transition
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Two Series Oxide Resistors Applicable to High Speed and High Density Nonvolatile Memory
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Frequency dependence of the thermal conductivity of semiconductor alloys
Koh, Y. K., & Cahill, D. G. (2007) · Physical Review B · doi:10.1103/physrevb.76.075207 · Cited by 383
Self-citationThermal conductivity of phase-change material Ge2Sb2Te5
Lyeo, H.-K., Cahill, D. G., Lee, B.-S., Abelson, J. R., Kwon, M.-H., Kim, K. B., Bishop, S. G., & Cheong, B. (2006) · Applied Physics Letters · doi:10.1063/1.2359354 · Cited by 316
Self-citationKoh, Y. K., Singer, S. L., Kim, W., Zide, J. M. O., Lü, H., Cahill, D. G., Majumdar, A., & Gossard, A. C. (2009) · Journal of Applied Physics · doi:10.1063/1.3078808 · Cited by 213
Self-citationInfrared spectroscopy and nano-imaging of the insulator-to-metal transition in vanadium dioxide
Qazilbash, M. M., Brehm, M., Andreev, G. O., Frenzel, A., Ho, P.-C., Chae, B. G., Kim, B.-J., Yun, S. J., Kim, H.-T., Balatsky, A. V., et al. (2009) · Physical Review B · doi:10.1103/physrevb.79.075107 · Cited by 203
Optical switching in VO2 films by below-gap excitation
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Chou, S. S., Kaehr, B., Kim, J., Foley, B. M., De, M., Hopkins, P. E., Huang, J., Brinker, C. J., & Dravid, V. P. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209229 · Cited by 692
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Recent progresses on physics and applications of vanadium dioxide
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Biological plausibility and stochasticity in scalable VO2 active memristor neurons
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Metadata
- Authors
- Oh, D.-W., Ko, C., Ramanathan, S., & Cahill, D. G.
- Affiliations
- University of Illinois Urbana-Champaign (US)
- Harvard University (US)
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2010-04-12
- Volume
- 96
- Issue
- 15
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2011656361
- Cited by
- 239
- References
- 18
- Citations by year
- 2026: 12 · 2025: 25 · 2024: 19 · 2023: 18 · 2022: 14 · 2021: 19 · 2020: 19 · 2019: 19 · 2018: 19 · 2017: 17 · 2016: 9 · 2015: 14 · 2014: 10 · 2013: 8 · 2012: 7
- FWCI
- 6.62
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Physics Letters (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Transition Metal Oxide Nanomaterials
- Physical Sciences › Materials Science › Materials Chemistry › Thermal properties of materials
- Physical Sciences › Engineering › Mechanics of Materials › Thermography and Photoacoustic Techniques
- Keywords
- vanadium dioxide, metal-insulator transition, thin films, thermal conductivity, dynamic heat capacity, time-domain thermoreflectance, electronic thermal conductivity, latent heat, phase transformation
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