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Modeling photocurrent action spectra of photovoltaic devices based on organic thin films

Pettersson, Leif A. A., Roman, Lucimara S., Inganäs, Olle·1999·Journal of Applied Physics

Abstract

We have modeled experimental short-circuit photocurrent action spectra of poly(3-(4′-(1″,4″,7″-trioxaoctyl)phenyl)thiophene) (PEOPT)/fullerene (C60) thin film heterojunction photovoltaic devices. Modeling was based on the assumption that the photocurrent generation process is the result of the creation and diffusion of photogenerated species (excitons), which are dissociated by charge transfer at the PEOPT/C60 interface. The internal optical electric field distribution inside the devices was calculated with the use of complex indices of refraction and layer thickness of the materials as determined by spectroscopic ellipsometry. Contributions to the photocurrent from optical absorption in polymer and fullerene layers were both necessary to model the experimental photocurrent action spectra. We obtained values for the exciton diffusion range of 4.7 and 7.7 nm for PEOPT and C60, respectively. The calculated internal optical electric field distribution and resulting photocurrent action spectra were used in order to study the influence of the geometrical structure with respect to the efficiency of the thin film devices. In this way the photocurrent was optimized.

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Metadata

Authors
Pettersson, L. A. A., Roman, L. S., & Inganäs, O.
Venue
Journal of Applied Physics
Published
1999-07-01
Volume
86
Issue
1
Pages
487-496
ISSN
  • 0021-8979 (ISSN-L)
  • 1089-7550
OpenAlex
W2005126509
Cited by
1,642
References
13
FWCI
8.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Modeling photocurrent action spectra of photovoltaic devices based on organic thin films. https://app.cochat.ai/papers/10.1063/1.370757
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Pettersson, L. A. A., Roman, L. S., & Inganäs, O. (1999). Modeling photocurrent action spectra of photovoltaic devices based on organic thin films. Journal of Applied Physics. https://doi.org/10.1063/1.370757

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.