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Theory of unsymmetric polymer–polymer interfaces
Abstract
Solutions have been obtained to equations which described the interface between two immiscible polymers and are more general than the equations first introduced by Helfand and Tagami. Gaussian random−walk statistics are assumed for the macromolecules. As a consequence of the present work, limitations of the earlier theory are removed, particularly the assumption that the properties of the two polymers when pure are identical. Calculations are performed for a variety of polymers and comparison with experiment is made.
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Citations
Cited by
Formation of dispersed phase in incompatible polymer blends: Interfacial and rheological effects
Wu, S. (1987) · Polymer Engineering & Science · doi:10.1002/pen.760270506 · Cited by 1,117
A Review of CO2 Applications in the Processing of Polymers
Tomasko, D. L., Li, H., Liu, D., Han, X., Wingert, M. J., Lee, L. J., & Koelling, K. W. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie030199z · Cited by 686
Ordering in thin films of block copolymers: Fundamentals to potential applications
Hamley, I. W. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.06.003 · Cited by 521
Walther, A., Matussek, K., & Müller, A. H. E. (2008) · ACS Nano · doi:10.1021/nn800108y · Cited by 310
Dynamic properties of interfaces in soft matter: Experiments and theory
Sagis, L. M. C. (2011) · Reviews of Modern Physics · doi:10.1103/revmodphys.83.1367 · Cited by 254
Metadata
- Authors
- Helfand, E., & Sapse, A. M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1975-02-15
- Volume
- 62
- Issue
- 4
- Pages
- 1327-1331
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2014544306
- Cited by
- 424
- References
- 0
- FWCI
- 15.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Theory of unsymmetric polymer–polymer interfaces. https://app.cochat.ai/papers/10.1063/1.430632
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- Helfand, E., & Sapse, A. M. (1975). Theory of unsymmetric polymer–polymer interfaces. The Journal of Chemical Physics. https://doi.org/10.1063/1.430632
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
