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Photofragmentation of symmetric triatomic molecules: Time dependent picture

Heller, Eric J.·1978·The Journal of Chemical Physics

Abstract

A recent time dependent formulation of total photodissociation cross sections is exploited to give a qualitative explanation of line shapes and absorption envelopes for symmetric triatomic (XY2) vacuum uv spectra. Attention is given to the dependence of the cross section on potential surface parameters and on the nature of the initial vibrational wavefunctions. The symmetric triatomic case treated here is illustrative of techniques which can be applied to more complicated, unsymmetric polyatomic situations.

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Metadata

Authors
Heller, E. J.
Venue
The Journal of Chemical Physics
Published
1978-04-15
Volume
68
Issue
8
Pages
3891-3896
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2009538472
Cited by
344
References
0
FWCI
6.99
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Photofragmentation of symmetric triatomic molecules: Time dependent picture. https://app.cochat.ai/papers/10.1063/1.436197
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Heller, E. J. (1978). Photofragmentation of symmetric triatomic molecules: Time dependent picture. The Journal of Chemical Physics. https://doi.org/10.1063/1.436197

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.