The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Surface roughness and the enhanced intensity of Raman scattering by molecules adsorbed on metals
Abstract
Greatly enhanced Raman scattering from monolayers of pyridine adsorbed on silver has been reported by several authors. I propose that the anomalous intensity arises from preresonant or resonant excitations of conduction electron resonances in adsorbate covered metal bumps on the surface. The bumps form a two-dimensional colliodlike layer which displays a collective resonance at a frequency which depends on the bump density. The model can account for the disparate excitation functions reported by two groups in terms of varying degrees of roughness. The apparent lack of enhancement with metals other than Group Ib is also explained.
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Citations
Cites
Raman spectra of pyridine adsorbed at a silver electrode
Fleischmann, M., Hendra, P. J., & McQuillan, A. J. (1974) · Chemical Physics Letters · doi:10.1016/0009-2614(74)85388-1 · Cited by 7,172
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Electromagnetic theory of enhanced Raman scattering by molecules adsorbed on rough surfaces
Gersten, J., & Nitzan, A. (1980) · The Journal of Chemical Physics · doi:10.1063/1.440560 · Cited by 1,084
Theoretical Studies of Plasmonics using Electronic Structure Methods
Morton, S. M., Silverstein, D. W., & Jensen, L. (2011) · Chemical Reviews · doi:10.1021/cr100265f · Cited by 474
Wu, D.-Y., Liu, X.-M., Huang, Y.-F., Ren, B., Xu, X., & Tian, Z.-Q. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9050929 · Cited by 311
Persistent misconceptions regarding SERS
Moskovits, M. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp44030j · Cited by 295
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Metadata
- Authors
- Moskovits, M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1978-11-01
- Volume
- 69
- Issue
- 9
- Pages
- 4159-4161
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2094273643
- Cited by
- 929
- References
- 2
- FWCI
- 40.01
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
