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The coordination (hydration) of rare earth ions in aqueous chloride solutions from x ray diffraction. I.TbCl3,DyCl3, ErCl3,TmCl3,and LuCl3
Abstract
The rare earth complex,[RE(H3O)8]3+,has been identified in concentrated (3.2−3.6 m) aqueous TbCl3,DyCl3,ErCl3,TmCl3, and LuCl3 solutions from x ray diffraction measurements. The inner sphere water coordination of rare earth ion was obtained from quantitative resolution of the radial distribution functions. In each solution the rare earth ion has eight water nearest neighbors with the average RE3−H2O distances being 2.409, 2.396, 2.369, 2.358, and 2.338Å for TbCl3,DyCl3, ErCl3, TmCl3, and LuCl3,respectively. The average RE3+. . . Cl− ion pair distances are near 4.8Å.
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Citations
Cited by
Li, P., Song, L. F., & Merz, K. M. (2015) · The Journal of Physical Chemistry B · doi:10.1021/jp505875v · Cited by 371
Revised Ionic Radii of Lanthanoid(III) Ions in Aqueous Solution
D’Angelo, P., Zitolo, A., Migliorati, V., Chillemi, G., Duvail, M., Vitorge, P., Abadie, S., & Spezia, R. (2011) · Inorganic Chemistry · doi:10.1021/ic200260r · Cited by 317
Periodic Behavior of Lanthanide Coordination within Reverse Micelles
Ellis, R. J., Meridiano, Y., Chiarizia, R., Berthon, L., Muller, J., Couston, L., & Antonio, M. R. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201202880 · Cited by 86
Metadata
- Authors
- Habenschuss, A., & Spedding, F. H.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1979-03-15
- Volume
- 70
- Issue
- 6
- Pages
- 2797-2806
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2080354595
- Cited by
- 269
- References
- 0
- FWCI
- 5.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: The coordination (hydration) of rare earth ions in aqueous chloride solutions from x ray diffraction. I.TbCl3,DyCl3, ErCl3,TmCl3,and LuCl3. https://app.cochat.ai/papers/10.1063/1.437866
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- Habenschuss, A., & Spedding, F. H. (1979). The coordination (hydration) of rare earth ions in aqueous chloride solutions from x ray diffraction. I.TbCl3,DyCl3, ErCl3,TmCl3,and LuCl3. The Journal of Chemical Physics. https://doi.org/10.1063/1.437866
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