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Cited by 203

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The dielectric relaxation time of supercooled water

Bertolini, D., Cassettari, M., Salvetti, G.·1982·The Journal of Chemical Physics

Abstract

The complex dielectric constant of liquid water was measured at 9.61 GHz down to −18 °C by means of a two resonant cavities apparatus. The static dielectric constant of bulk samples was also measured at 27.5 MHz down to −16.5 °C using a resonant circuit technique. From the analysis of the experimental results it follows that water in the metastable region has practically a single dielectric relaxation time τ. An analysis of the dynamic properties of water using our results and available data in literature, is presented. The main result is that self-diffusion DS, shear viscosity η, and τ below 0 °C are related to the same mechanism. For T≳0°C another mechanism affecting η rises.

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Metadata

Authors
Bertolini, D., Cassettari, M., & Salvetti, G.
Venue
The Journal of Chemical Physics
Published
1982-03-15
Volume
76
Issue
6
Pages
3285-3290
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W1998391450
Cited by
203
References
1
FWCI
6.75
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The dielectric relaxation time of supercooled water. https://app.cochat.ai/papers/10.1063/1.443323
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Bertolini, D., Cassettari, M., & Salvetti, G. (1982). The dielectric relaxation time of supercooled water. The Journal of Chemical Physics. https://doi.org/10.1063/1.443323

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