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The dielectric relaxation time of supercooled water
Abstract
The complex dielectric constant of liquid water was measured at 9.61 GHz down to −18 °C by means of a two resonant cavities apparatus. The static dielectric constant of bulk samples was also measured at 27.5 MHz down to −16.5 °C using a resonant circuit technique. From the analysis of the experimental results it follows that water in the metastable region has practically a single dielectric relaxation time τ. An analysis of the dynamic properties of water using our results and available data in literature, is presented. The main result is that self-diffusion DS, shear viscosity η, and τ below 0 °C are related to the same mechanism. For T≳0°C another mechanism affecting η rises.
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Citations
Cites
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole, K. S., & Cole, R. H. (1941) · The Journal of Chemical Physics · doi:10.1063/1.1750906 · Cited by 10,152
Cited by
The complex dielectric constant of pure and sea water from microwave satellite observations
Meissner, T., & Wentz, F. J. (2004) · IEEE Transactions on Geoscience and Remote Sensing · doi:10.1109/tgrs.2004.831888 · Cited by 803
Stern, H. A., Rittner, F., Berne, B. J., & Friesner, R. A. (2001) · The Journal of Chemical Physics · doi:10.1063/1.1376165 · Cited by 275
Metadata
- Authors
- Bertolini, D., Cassettari, M., & Salvetti, G.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1982-03-15
- Volume
- 76
- Issue
- 6
- Pages
- 3285-3290
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1998391450
- Cited by
- 203
- References
- 1
- FWCI
- 6.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bertolini, D., Cassettari, M., & Salvetti, G. (1982). The dielectric relaxation time of supercooled water. The Journal of Chemical Physics. https://doi.org/10.1063/1.443323
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