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Kinetics of phase transitions: Theory of Ostwald ripening
Abstract
A new derivation is presented for the last stage of phase separation in the kinetics of a first order phase transition, precipitation, where Ostwald ripening is the dominant mechanism. We use a time scaling technique and derive the power law time dependence and distribution function for the size of the particles of the new phase. Equations are derived for the correction terms to the distribution function and power laws. The derivation clarifies and corrects prior work.
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Cited by
The theory of Ostwald ripening
Voorhees, P. W. (1985) · Journal of Statistical Physics · doi:10.1007/bf01017860 · Cited by 2,087
Steefel, C. I., & Van Cappellen, P. (1990) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(90)90003-4 · Cited by 548
Degradation of kinetically-stable o/w emulsions
Capek, I. (2004) · Advances in Colloid and Interface Science · doi:10.1016/s0001-8686(03)00115-5 · Cited by 377
How subtle changes in 3D structure can create large changes in transcription
Xiao, J. Y., Hafner, A., & Boettiger, A. N. (2021) · eLife · doi:10.7554/elife.64320 · Cited by 162
Metadata
- Authors
- Marqusee, J. A., & Ross, J.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1983-07-01
- Volume
- 79
- Issue
- 1
- Pages
- 373-378
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2014019046
- Cited by
- 280
- References
- 0
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Kinetics of phase transitions: Theory of Ostwald ripening. https://app.cochat.ai/papers/10.1063/1.445532
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- Marqusee, J. A., & Ross, J. (1983). Kinetics of phase transitions: Theory of Ostwald ripening. The Journal of Chemical Physics. https://doi.org/10.1063/1.445532
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.