The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Solvent influence on photoisomerization dynamicsa)
Abstract
The rate constants of the nonradiative decay process of the excited singlet state of trans-stilbene and trans-1,1′-biindanylidene (‘‘stiff ’’ stilbene) were measured in liquid n-alkanes at room temperature. These data were compared with the two models for isomerization in condensed phases proposed by Kramers and by Grote and Hynes. For trans-stilbene, the agreement with Kramers’ model was unsatisfactory, whereas better agreement was obtained with Grote and Hynes’ model. The data for stiff stilbene agreed well with Kramers’ model in the Smoluchowski limit. These results were explained in terms of the shape of the potential energy barrier which separates the trans from the twisted configuration of the excited singlet state of these molecules. It is suggested that the deviation between theory and experiment is a result of a qualitative difference in the microscopic solvent–solute collisional interaction when the solvent molecules are longer than stilbene. The best fit of theory to experiment for trans-stilbene requires the use of an unphysically low (8 cm−1) frequency for the top of the barrier to isomerization.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Brownian motion in a field of force and the diffusion model of chemical reactions
Kramers, H. A. (1940) · Physica · doi:10.1016/s0031-8914(40)90098-2 · Cited by 8,625
Stochastic Problems in Physics and Astronomy
Chandrasekhar, S. (1943) · Reviews of Modern Physics · doi:10.1103/revmodphys.15.1 · Cited by 8,470
The fluctuation-dissipation theorem
Kubo, R. (1966) · Reports on Progress in Physics · doi:10.1088/0034-4885/29/1/306 · Cited by 5,094
Measurement of photoluminescence quantum yields. Review
Crosby, G. A., & Demas, J. N. (1971) · The Journal of Physical Chemistry · doi:10.1021/j100678a001 · Cited by 4,870
Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules
Strickler, S. J., & Berg, R. A. (1962) · The Journal of Chemical Physics · doi:10.1063/1.1733166 · Cited by 2,481
Low Reynolds number hydrodynamics: with special applications to particulate media
Happel, J., & Brenner, H. (1983) · Mechanics of fluids and transport processes · doi:10.1007/978-94-009-8352-6 · Cited by 1,354
Grote, R. F., & Hynes, J. T. (1980) · The Journal of Chemical Physics · doi:10.1063/1.440485 · Cited by 1,338
Selected Values of Physical and Thermodynamic Properties of Hydrocarbons and Related Compounds.
Parks, G. S. (1954) · Journal of the American Chemical Society · doi:10.1021/ja01636a111 · Cited by 835
Molecular dynamics of liquid alkanes
Ryckaert, J.-P., & Bellemans, A. (1978) · Faraday Discussions of the Chemical Society · doi:10.1039/dc9786600095 · Cited by 710
Cited by
Reaction-rate theory: fifty years after Kramers
Hänggi, P., Talkner, P., & Borkovec, M. (1990) · Reviews of Modern Physics · doi:10.1103/revmodphys.62.251 · Cited by 6,154
Solvation in Supercritical Fluids: Its Effects on Energy Transfer and Chemical Reactions
Kajimoto, O. (1999) · Chemical Reviews · doi:10.1021/cr970031l · Cited by 366
Fast Dynamics and Stabilization of Proteins: Binary Glasses of Trehalose and Glycerol
Cicerone, M. T., & Soles, C. L. (2004) · Biophysical Journal · doi:10.1529/biophysj.103.035519 · Cited by 275
Metadata
- Authors
- Rothenberger, G., Negus, D. K., & Hochstrasser, R. M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1983-12-01
- Volume
- 79
- Issue
- 11
- Pages
- 5360-5367
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2018293901
- Cited by
- 290
- References
- 19
- FWCI
- 21.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rothenberger, G., Negus, D. K., & Hochstrasser, R. M. (1983). Solvent influence on photoisomerization dynamicsa). The Journal of Chemical Physics. https://doi.org/10.1063/1.445699
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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