The DOI matches its Crossref record; the references it cites are not checked yet.
Spin-dependent electrochemical kinetics at a semiconducting photocathode
Abstract
We present experimental evidence that the electrochemical rate at a semiconducting photocathode can be affected by the relative spin orientations of the electrons in the semiconductor and of the redox species in the electrolyte. Here the spin orientations are acted upon independently by combination of a large magnetic field and optical pumping of the photoelectrons with circularly polarized light. The effect can be qualitatively understood in terms of the classical models for electrochemical transfer at a semiconducting photoelectrode. The results show that the spin polarization may not be drastically affected upon the electrochemical transfer and may provide a probe for the electrochemical interface.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
The citation lists haven’t been fetched yet
References 27 · Cited by 8
Research works printed but not linked: 29
- 1980, Electrochem. Acta, 25, 29, 10.1016/0013-4686(80)80051-X · DOI
- 1981, J. Am. Chem. Soc., 102, 3671
- 1981, Appl. Phys. Lett., 38, 282, 10.1063/1.92307 · DOI
- 1982, J. Electrochem. Soc., 129, 730, 10.1149/1.2123961 · DOI
- 1985, J. Electrochem. Soc., 132, 45, 10.1149/1.2113788 · DOI
- 1972, Phys. Rev. B, 6, 436, 10.1103/PhysRevB.6.436 · DOI
- 1976, Solid State Commun., 20, 215, 10.1016/0038-1098(76)90179-4 · DOI
- 1978, J. Phys. (Paris), 39, L51, 10.1051/jphyslet:0197800390405100 · DOI
- 1968, Phys. Rev. Lett., 20, 491, 10.1103/PhysRevLett.20.491 · DOI
- 1977, Phys. Rev. B, 15, 816, 10.1103/PhysRevB.15.816 · DOI
- 1977, J. Appl. Phys., 48, 4292, 10.1063/1.323417 · DOI
- 1980, Appl. Phys. Lett., 36, 574, 10.1063/1.91551 · DOI
- 1978, J. Electrochem. Soc., 125, 937, 10.1149/1.2131595 · DOI
- 1982, J. Electrochem. Soc., 129, 1134, 10.1149/1.2124042 · DOI
- 1983, J. Electrochem. Soc., 130, 1699, 10.1149/1.2120065 · DOI
- 1982, J. Electrochem. Soc., 129, 963, 10.1149/1.2124074 · DOI
- 1959, Phys. Rev., 116, 84, 10.1103/PhysRev.116.84 · DOI
- 1969, Surf. Sci., 18, 97, 10.1016/0039-6028(69)90269-6 · DOI
- 1957, Proc. IRE, 45, 1228, 10.1109/JRPROC.1957.278528 · DOI
- 1977, Phys. Rev. B, 16, 820, 10.1103/PhysRevB.16.820 · DOI
- 1983, Zh. Eksp. Teor. Fiz., 84, 1170
- 1983, Sov. Phys. JETP, 57, 680
- 1976, Phys. Rev. B, 13, 5484, 10.1103/PhysRevB.13.5484 · DOI
- 1973, J. Electrochem. Soc., 120, 1385, 10.1149/1.2403267 · DOI
- 1981, J. Am. Chem. Soc., 103, 7447, 10.1021/ja00415a008 · DOI
- 1982, J. Appl. Phys., 53, R123, 10.1063/1.331665 · DOI · Paper page
- 1984, Phys. Rev. B, 30, 931, 10.1103/PhysRevB.30.931 · DOI
- 1979, J. Electrochem. Soc., 126, 598, 10.1149/1.2129093 · DOI
- 1983, J. Electrochem. Soc., 130, 1680, 10.1149/1.2120062 · DOI
Metadata
- Authors
- Chazalviel, J.-N.
- Affiliations
- École Polytechnique (FR)
- Corresponding author
- Chazalviel, J.-N.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1985-07-01
- Volume
- 83
- Issue
- 1
- Pages
- 149-156
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2013265014
- Cited by
- 8
- References
- 27
- Citations by year
- 2026: 1 · 2020: 1 · 2019: 2
- FWCI
- 0.24
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Chemical Physics (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Condensed Matter Physics › Quantum and electron transport phenomena
- Physical Sciences › Physics and Astronomy › Instrumentation › Photocathodes and Microchannel Plates
- Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
- Keywords
- photoelectrodes, spin polarization, electron spin orientation, redox species, magnetic field effects, circularly polarized light, optical pumping, electron transfer, electrochemical interfaces
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Spin-dependent electrochemical kinetics at a semiconducting photocathode. https://app.cochat.ai/papers/10.1063/1.449797
- The paper
- Chazalviel, J.-N. (1985). Spin-dependent electrochemical kinetics at a semiconducting photocathode. The Journal of Chemical Physics. https://doi.org/10.1063/1.449797
