The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Study on dynamical structure in water and heavy water by low-frequency Raman spectroscopy
Abstract
Depolarized Raman spectra below 250 cm−1 in water and heavy water were measured and analyzed from 373 K to the supercooled region. The spectral feature of the central component below 20 cm−1 is stressed in the present work. The spectra below 250 cm−1 in water and heavy water are interpreted as a superposition of one Debye-type relaxation mode and two damped harmonic oscillators. The damped harmonic oscillators (broadbands around 60 cm−1 and 190 cm−1) are interpreted as the restricted translational modes. Analyzing the temperature dependence of the relaxation mode, the reciprocal relaxation time τ−1 in heavy water changes linearly with τ−1 ∝ (T − 240 K) in the whole temperature range. On the other hand, the temperature dependence of the reciprocal relaxation time in water above 303 K deviates from a straight line which holds below 298 K as τ−1 ∝ (T − 225 K).
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Citations
Cites
Large local energy fluctuations in water. II. Cooperative motions and fluctuations
Ohmine, I., Tanaka, H., & Wolynes, P. G. (1988) · The Journal of Chemical Physics · doi:10.1063/1.455536 · Cited by 216
Cited by
THz reflection spectroscopy of liquid water
Thrane, L., Jacobsen, R. H., Uhd Jepsen, P., & Keiding, S. R. (1995) · Chemical Physics Letters · doi:10.1016/0009-2614(95)00543-d · Cited by 339
Nishi, N., Nakabayashi, T., & Kosugi, K. (1999) · The Journal of Physical Chemistry A · doi:10.1021/jp9929061 · Cited by 78
Metadata
- Authors
- Mizoguchi, K., Hori, Y., & Tominaga, Y.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1992-08-01
- Volume
- 97
- Issue
- 3
- Pages
- 1961-1968
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2038930615
- Cited by
- 160
- References
- 1
- FWCI
- 6.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mizoguchi, K., Hori, Y., & Tominaga, Y. (1992). Study on dynamical structure in water and heavy water by low-frequency Raman spectroscopy. The Journal of Chemical Physics. https://doi.org/10.1063/1.463133
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