The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Colloids dispersed in polymer solutions. A computer simulation study
Open accessAbstract
We report a computer-simulation study of a simple model for a colloid dispersed in a polymer solution. The simulations were performed using a computational scheme that allows simulation at constant osmotic pressure of the polymers. We present results for the polymer-induced interaction, the equation-of-state, and the phase diagram. The simulations show that when the radius of gyration of the polymers Rg is sufficiently large compared to the diameter of the colloidal particles σcol (2Rg/σcol≥0.45), addition of polymer induces a colloidal ‘‘liquid–vapor’’ phase separation. For shorter polymers, only the solid–fluid transition is observed. In addition, we find that the nonpairwise additivity of the polymer-induced attraction between the colloidal particles has a pronounced effect on the equation-of-state and the phase behavior of a colloid–polymer mixture. The perturbation theory of Lekkerkerker et al. [Europhys. Lett. 20, 559 (1992)] is found to perform well, except at low densities.
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Cites
Statistical mechanics of chain molecules
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Equation of State for Nonattracting Rigid Spheres
Carnahan, N. F., & Starling, K. E. (1969) · The Journal of Chemical Physics · doi:10.1063/1.1672048 · Cited by 5,280
High-Temperature Equation of State by a Perturbation Method. I. Nonpolar Gases
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Widom, B. (1963) · The Journal of Chemical Physics · doi:10.1063/1.1734110 · Cited by 3,035
On Interaction between Two Bodies Immersed in a Solution of Macromolecules
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Statistical Mechanics of Rigid Spheres
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Complex plasmas: An interdisciplinary research field
Morfill, G. E., & Ivlev, A. V. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.1353 · Cited by 803
Integral Equation Theories of the Structure, Thermodynamics, and Phase Transitions of Polymer Fluids
Schweizer, K. S., & Curro, J. G. (1997) · Advances in Chemical Physics · doi:10.1002/9780470141571.ch1 · Cited by 386
Depletion-induced phase separation in colloid–polymer mixtures
Tuinier, R., Rieger, J., & de Kruif, C. G. (2003) · Advances in Colloid and Interface Science · doi:10.1016/s0001-8686(02)00081-7 · Cited by 357
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Metadata
- Authors
- Meijer, E. J., & Frenkel, D.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1994-05-01
- Volume
- 100
- Issue
- 9
- Pages
- 6873-6887
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2008384883
- Cited by
- 301
- References
- 18
- FWCI
- 16.80
- Type
- journal article
- Language
- en
- Open access
- green
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
