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Measurement of the Raman spectrum of liquid water
Abstract
The Raman spectrum from water was obtained for a range of conditions from ambient to above the critical point, 256 bar and 400 °C. A fluorescence-free sapphire high-pressure Raman cell was employed with which the Raman spectra from water were examined between 30 and 4000 cm−1. Computer deconvolution of the Raman OH-stretching contours allowed the hydrogen bond strength to be determined from the integrated component intensity ratios by use of the van’t Hoff relationship. This procedure yielded a hydrogen bond enthalpy of 2.53±0.10 kcal/mol which is in excellent agreement with previously reported values.
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Cited by
Microstructures and Spectroscopic Properties of Cryptomelane-type Manganese Dioxide Nanofibers
Gao, T., Glerup, M., Krumeich, F., Nesper, R., Fjellvåg, H., & Norby, P. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804924f · Cited by 473
Shedding light onto the spectra of lime: Raman and luminescence bands of CaO, Ca(OH)2 and CaCO3
Schmid, T., & Dariz, P. (2015) · Journal of Raman Spectroscopy · doi:10.1002/jrs.4622 · Cited by 162
Moniri, S., Hantehzadeh, M. R., Ghoranneviss, M., & Asadabad, M. A. (2017) · Applied Physics A · doi:10.1007/s00339-017-1311-9 · Cited by 20
Metadata
- Authors
- Carey, D. M., & Korenowski, G. M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1998-02-15
- Volume
- 108
- Issue
- 7
- Pages
- 2669-2675
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1964621160
- Cited by
- 645
- References
- 0
- FWCI
- 7.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Carey, D. M., & Korenowski, G. M. (1998). Measurement of the Raman spectrum of liquid water. The Journal of Chemical Physics. https://doi.org/10.1063/1.475659
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