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Exciton-migration and three-pulse femtosecond optical spectroscopies of photosynthetic antenna complexes
Abstract
A theory for four-wave-mixing signals from molecular aggregates, which includes effects of two-exciton states, static disorder, and coupling to a phonon bath with an arbitrary spectral density, is developed. The third-order polarization is rigorously partitioned into a coherent and a sequential contribution. The latter is given by a sum of an exciton-hopping and a ground state (bleaching) terms, both expressed using the doorway-window representation. Applications are made to photon-echo and pump-probe spectroscopies of the B850 system of the LH2 antenna in purple bacteria.
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Citations
Cited by
Two-dimensional spectroscopy of electronic couplings in photosynthesis
Brixner, T., Stenger, J., Vaswani, H. M., Cho, M., Blankenship, R. E., & Fleming, G. R. (2005) · Nature · doi:10.1038/nature03429 · Cited by 1,241
Environment-assisted quantum walks in photosynthetic energy transfer
Mohseni, M., Rebentrost, P., Lloyd, S., & Aspuru-Guzik, A. (2008) · The Journal of Chemical Physics · doi:10.1063/1.3002335 · Cited by 1,189
Multidimensional Femtosecond Correlation Spectroscopies of Electronic and Vibrational Excitations
Mukamel, S. (2000) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.51.1.691 · Cited by 894
Self-citationCoherent Two-Dimensional Optical Spectroscopy
Cho, M. (2008) · Chemical Reviews · doi:10.1021/cr078377b · Cited by 835
Ishizaki, A., & Fleming, G. R. (2009) · The Journal of Chemical Physics · doi:10.1063/1.3155372 · Cited by 734
Metadata
- Authors
- Zhang, W. M., Meier, T., Chernyak, V., & Mukamel, S.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1998-05-08
- Volume
- 108
- Issue
- 18
- Pages
- 7763-7774
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2097668319
- Cited by
- 413
- References
- 0
- FWCI
- 9.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, W. M., Meier, T., Chernyak, V., & Mukamel, S. (1998). Exciton-migration and three-pulse femtosecond optical spectroscopies of photosynthetic antenna complexes. The Journal of Chemical Physics. https://doi.org/10.1063/1.476212
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