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Electrical field profile and doping in planar lead halide perovskite solar cells

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Guerrero, Antonio, Juarez-Perez, Emilio J., Bisquert, Juan, Mora-Sero, Ivan, Garcia-Belmonte, Germà·2014·Applied Physics Letters

Abstract

Hybrid lead halide perovskites (PVKs) have emerged as novel materials for photovoltaics and have rapidly reached very large solar to electricity power conversion efficiencies. As occurring with other kind of solar technologies establishing the working energy-band diagram constitutes a primary goal for device physics analysis. Here, the macroscopic electrical field distribution is experimentally determined using capacitance-voltage and Kelvin probe techniques. Planar structures comprising CH3NH3PbI3−xClx PVK exhibit p-doping character and form a p-n heterojunction with n-doped TiO2 compact layers. Depletion width at equilibrium within the PVK bulk has an extent about 300 nm (approximately half of the layer thickness), leaving as a consequence a significant neutral zone towards the anode contact. Charge collection properties are then accessible relying on the relative weight that diffusion and drift have as carrier transport driven forces.

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Metadata

Authors
Guerrero, A., Juarez-Perez, E. J., Bisquert, J., Mora-Sero, I., & Garcia-Belmonte, G.
Venue
Applied Physics Letters
Published
2014-09-29
Volume
105
Issue
13
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2052756665
Cited by
192
References
1
FWCI
13.27
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Electrical field profile and doping in planar lead halide perovskite solar cells. https://app.cochat.ai/papers/10.1063/1.4896779
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Guerrero, A., Juarez-Perez, E. J., Bisquert, J., Mora-Sero, I., & Garcia-Belmonte, G. (2014). Electrical field profile and doping in planar lead halide perovskite solar cells. Applied Physics Letters. https://doi.org/10.1063/1.4896779

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