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Electrical field profile and doping in planar lead halide perovskite solar cells
Open accessAbstract
Hybrid lead halide perovskites (PVKs) have emerged as novel materials for photovoltaics and have rapidly reached very large solar to electricity power conversion efficiencies. As occurring with other kind of solar technologies establishing the working energy-band diagram constitutes a primary goal for device physics analysis. Here, the macroscopic electrical field distribution is experimentally determined using capacitance-voltage and Kelvin probe techniques. Planar structures comprising CH3NH3PbI3−xClx PVK exhibit p-doping character and form a p-n heterojunction with n-doped TiO2 compact layers. Depletion width at equilibrium within the PVK bulk has an extent about 300 nm (approximately half of the layer thickness), leaving as a consequence a significant neutral zone towards the anode contact. Charge collection properties are then accessible relying on the relative weight that diffusion and drift have as carrier transport driven forces.
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Cites
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
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Brenner, T. M., Egger, D. A., Kronik, L., Hodes, G., & Cahen, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.7 · Cited by 1,557
Tress, W., Marinova, N., Moehl, T., Zakeeruddin, S. M., Nazeeruddin, M. K., & Grätzel, M. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03664f · Cited by 1,381
Tress, W. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602358 · Cited by 601
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
Ono, L. K., Juarez-Perez, E. J., & Qi, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06001 · Cited by 593
Self-citationAlmora, O., Aranda, C., Mas-Marzá, E., & Garcia-Belmonte, G. (2016) · Applied Physics Letters · doi:10.1063/1.4966127 · Cited by 543
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Metadata
- Authors
- Guerrero, A., Juarez-Perez, E. J., Bisquert, J., Mora-Sero, I., & Garcia-Belmonte, G.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2014-09-29
- Volume
- 105
- Issue
- 13
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2052756665
- Cited by
- 192
- References
- 1
- FWCI
- 13.27
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Guerrero, A., Juarez-Perez, E. J., Bisquert, J., Mora-Sero, I., & Garcia-Belmonte, G. (2014). Electrical field profile and doping in planar lead halide perovskite solar cells. Applied Physics Letters. https://doi.org/10.1063/1.4896779
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