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Strong spin-lattice coupling in CrSiTe3

Open access
Casto, L. D., Clune, A. J., Yokosuk, M. O., Musfeldt, J. L., Williams, T. J., Zhuang, H. L., Lin, M.-W., Xiao, K., Hennig, R. G., Sales, B. C., Yan, J.-Q., Mandrus, D.·2015·APL Materials

Abstract

CrSiTe3 has attracted recent interest as a candidate single-layer ferromagnetic semiconductor, but relatively little is known about the bulk properties of this material. Here, we report single-crystal X-ray diffraction, magnetic properties, thermal conductivity, vibrational, and optical spectroscopies and compare our findings with complementary electronic structure and lattice dynamics principles calculations. The high temperature paramagnetic phase is characterized by strong spin-lattice interactions that give rise to glassy behavior, negative thermal expansion, and an optical response that reveals that CrSiTe3 is an indirect gap semiconductor with indirect and direct band gaps at 0.4 and 1.2 eV, respectively. Measurements of the phonons across the 33 K ferromagnetic transition provide additional evidence for strong coupling between the magnetic and lattice degrees of freedom. The Si-Te stretching and Te displacement modes are sensitive to the magnetic ordering transition, a finding that we discuss in terms of the superexchange mechanism. Spin-lattice coupling constants are also extracted.

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Metadata

Authors
Casto, L. D., Clune, A. J., Yokosuk, M. O., Musfeldt, J. L., Williams, T. J., Zhuang, H. L., Lin, M.-W., Xiao, K., Hennig, R. G., Sales, B. C., Yan, J.-Q., & Mandrus, D.
Venue
APL Materials
Published
2015-03-19
Volume
3
Issue
4
ISSN
2166-532X (ISSN-L)
OpenAlex
W2109210841
Cited by
265
References
3
FWCI
9.75
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Strong spin-lattice coupling in CrSiTe3. https://app.cochat.ai/papers/10.1063/1.4914134
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Casto, L. D., Clune, A. J., Yokosuk, M. O., Musfeldt, J. L., Williams, T. J., Zhuang, H. L., Lin, M.-W., Xiao, K., Hennig, R. G., Sales, B. C., Yan, J.-Q., & Mandrus, D. (2015). Strong spin-lattice coupling in CrSiTe3. APL Materials. https://doi.org/10.1063/1.4914134

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.