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Rate constants for the decay and reactions of the lowest electronically excited singlet state of molecular oxygen in solution
Abstract
The available rate data on the reactivity and physical deactivation of molecular oxygen in its first electronic excited state (1Δg) in liquid solution have been critically compiled. Where possible, relative rates reported in the literature have been normalized to standard values selected by a statistical analysis of the experimental data. Second order rate constants for the deactivation and chemical reaction of singlet oxygen are reported for 670 compounds. Additionally, psuedo first order rate constants (kd) for solvent deactivation of singlet oxygen are reported for 50 different solvents.
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Citations
Cited by
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Schweitzer, C., & Schmidt, R. (2003) · Chemical Reviews · doi:10.1021/cr010371d · Cited by 2,123
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Gomes, A., Fernandes, E., & Lima, J. L. F. C. (2005) · Journal of Biochemical and Biophysical Methods · doi:10.1016/j.jbbm.2005.10.003 · Cited by 1,844
The oxidative environment and protein damage
Davies, M. J. (2005) · Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics · doi:10.1016/j.bbapap.2004.08.007 · Cited by 1,392
Schmidt, R., Tanielian, C., Dunsbach, R., & Wolff, C. (1994) · Journal of Photochemistry and Photobiology A: Chemistry · doi:10.1016/1010-6030(93)03746-4 · Cited by 580
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Pattison, D. I., & Davies, M. J. (2006) · Experientia Supplementum · doi:10.1007/3-7643-7378-4_6 · Cited by 283
Metadata
- Authors
- Wilkinson, F., & Brummer, J. G.
- Venue
- Journal of Physical and Chemical Reference Data
- Publisher
- AIP Publishing
- Published
- 1981-10-01
- Volume
- 10
- Issue
- 4
- Pages
- 809-999
- ISSN
- 0047-2689 (ISSN-L)
- 1529-7845
- OpenAlex
- W2068765991
- Cited by
- 564
- References
- 0
- FWCI
- 9.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Rate constants for the decay and reactions of the lowest electronically excited singlet state of molecular oxygen in solution. https://app.cochat.ai/papers/10.1063/1.555655
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- Wilkinson, F., & Brummer, J. G. (1981). Rate constants for the decay and reactions of the lowest electronically excited singlet state of molecular oxygen in solution. Journal of Physical and Chemical Reference Data. https://doi.org/10.1063/1.555655
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