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A Fundamental Equation of State for Heavy Water
Abstract
A fundamental equation of state has been formulated for heavy water in the form Ψ = Ψ(p,T) in which Ψ = Helmholtz free energy p = density T = thermodynamic temperature. The complete range of single phase states in the range up to 100 MPa and 600 °C is covered by a single equation which is fitted both to PvT values, for saturated and unsaturated states, and to enthalpy values for saturation states only. The equation is constrained to fit the critical point conditions determined by Blank. It represents all thermodynamic properties of D2O, in the above range of states, within what is believed to be the accuracy of the experimental data.
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Cited by
Fredrickson, J. K., Zachara, J. M., Kennedy, D. W., Dong, H., Onstott, T. C., Hinman, N. W., & Li, S.-M. (1998) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(98)00243-9 · Cited by 807
Thermodynamic constraints on hydrogen generation during serpentinization of ultramafic rocks
McCollom, T. M., & Bach, W. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.10.032 · Cited by 632
Origins of building blocks of life: A review
Kitadai, N., & Maruyama, S. (2018) · Geoscience Frontiers · doi:10.1016/j.gsf.2017.07.007 · Cited by 464
Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review
Cornelis, G., Johnson, C. A., Gerven, T. V., & Vandecasteele, C. (2008) · Applied Geochemistry · doi:10.1016/j.apgeochem.2008.02.001 · Cited by 391
FTIR Study of CO2 Adsorption on Amine-Grafted SBA-15: Elucidation of Adsorbed Species
Danon, A., Stair, P. C., & Weitz, E. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp200914v · Cited by 361
Metadata
- Authors
- Hill, P. G., MacMillan, R. D. C., & Lee, V.
- Venue
- Journal of Physical and Chemical Reference Data
- Publisher
- AIP Publishing
- Published
- 1982-01-01
- Volume
- 11
- Issue
- 1
- Pages
- 1-14
- ISSN
- 0047-2689 (ISSN-L)
- 1529-7845
- OpenAlex
- W2003685350
- Cited by
- 1,503
- References
- 0
- FWCI
- 10.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hill, P. G., MacMillan, R. D. C., & Lee, V. (1982). A Fundamental Equation of State for Heavy Water. Journal of Physical and Chemical Reference Data. https://doi.org/10.1063/1.555661
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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