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Evaluation of Kinetic and Mechanistic Data for Modeling of Photochemical Smog
Abstract
This review is a critical evaluation of the rate constants, mechanisms, and products of selected atmospheric reactions of hydrocarbons, nitrogen oxides, and sulfur oxides in air. The evaluation considers eight hydrocarbons (n-butane, 2,3-dimethylbutane, ethene, propene, 1-butene, trans-2-butene, toluene, and m-xylene) for which smog chamber irradiations have been carried out under carefully controlled conditions and which have been the subject of computer modeling studies by more than one research group. The reactions involved are treated in the following categories: inorganic reactions in organic-NOx-air irradiations; organic reactions of the formaldehyde-NOx-air system; organic reactions of the acetaldehyde-NOx-air system; organic reactions of the alkene-NOx-air systems; organic reactions of the alkane-NOx-air systems; organic reactions of selected carbonyl-NOx-air systems; organic reactions of the aromatic-NOx-air systems; combination reactions of peroxy radicals, and homogeneous gas phase SO2 reactions. This report considers literature through early 1983.
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Citations
Cited by
A detailed mechanism for the gas-phase atmospheric reactions of organic compounds
Carter, W. P. L. (1990) · Atmospheric Environment. Part A. General Topics · doi:10.1016/0960-1686(90)90005-8 · Cited by 538
The atmospheric chemistry of organic nitrates
Roberts, J. M. (1990) · Atmospheric Environment. Part A. General Topics · doi:10.1016/0960-1686(90)90108-y · Cited by 470
Development of a two-dimensional global tropospheric model: model chemistry
Hough, A. M. (1991) · Journal of Geophysical Research Atmospheres · doi:10.1029/90jd01327 · Cited by 169
Metadata
- Authors
- Atkinson, R., & Lloyd, A. C.
- Venue
- Journal of Physical and Chemical Reference Data
- Publisher
- AIP Publishing
- Published
- 1984-04-01
- Volume
- 13
- Issue
- 2
- Pages
- 315-444
- ISSN
- 0047-2689 (ISSN-L)
- 1529-7845
- OpenAlex
- W2020678016
- Cited by
- 481
- References
- 0
- FWCI
- 26.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Evaluation of Kinetic and Mechanistic Data for Modeling of Photochemical Smog. https://app.cochat.ai/papers/10.1063/1.555710
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- Atkinson, R., & Lloyd, A. C. (1984). Evaluation of Kinetic and Mechanistic Data for Modeling of Photochemical Smog. Journal of Physical and Chemical Reference Data. https://doi.org/10.1063/1.555710
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
