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Proton exchange for high-index waveguides in LiNbO3

Jackel, J. L., Rice, C. E., Veselka, J. J.·1982·Applied Physics Letters

Abstract

We describe the fabrication and characterization of optical waveguides formed in LiNbO3 by proton exchange in benzoic acid melts at 200–250 °C. Proton exchange, in LiNbO3 the replacement of lithium ions with protons, takes place when the substrate is immersed in the molten acid. We observe a surface increase in the refractive index of 0.12, for the extraordinary polarization only, with a step function index profile. This is the highest index increase obtainable to date for LiNbO3. Measured diffusion rates for x-cut crystals are 1.37 μm2/h at T = 249 °C and 0.37 μm2/h at T = 217 °C, so that very deep guides can be formed in short times. Diffusion is somewhat slower in the z direction. The process as described is not useful for y-cut crystals, since it damgaes this surface. Losses, measured on x-cut samples, were <0.5 dB/cm. All measurements were made at 0.633 μm.

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Metadata

Authors
Jackel, J. L., Rice, C. E., & Veselka, J. J.
Venue
Applied Physics Letters
Published
1982-10-01
Volume
41
Issue
7
Pages
607-608
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2090973546
Cited by
693
References
0
FWCI
10.55
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Proton exchange for high-index waveguides in LiNbO3. https://app.cochat.ai/papers/10.1063/1.93615
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Jackel, J. L., Rice, C. E., & Veselka, J. J. (1982). Proton exchange for high-index waveguides in LiNbO3. Applied Physics Letters. https://doi.org/10.1063/1.93615

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