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Directional Weak Intermolecular Interactions: σ-Hole Bonding

Murray, Jane S., Riley, Kevin E., Politzer, Peter, Clark, Timothy·2010·Australian Journal of Chemistry

Abstract

The prototypical directional weak interactions, hydrogen bonding and σ-hole bonding (including the special case of halogen bonding) are reviewed in a united picture that depends on the anisotropic nature of the molecular electrostatic potential around the donor atom. Qualitative descriptions of the effects that lead to these anisotropic distributions are given and examples of the importance of σ-hole bonding in crystal engineering and biological systems are discussed.

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Metadata

Authors
Murray, J. S., Riley, K. E., Politzer, P., & Clark, T.
Venue
Australian Journal of Chemistry
Published
2010-12-06
Volume
63
Issue
12
Pages
1598-1607
ISSN
  • 0004-9425 (ISSN-L)
  • 1445-0038
OpenAlex
W2094294679
Cited by
251
References
0
FWCI
18.89
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Directional Weak Intermolecular Interactions: σ-Hole Bonding. https://app.cochat.ai/papers/10.1071/ch10259
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Murray, J. S., Riley, K. E., Politzer, P., & Clark, T. (2010). Directional Weak Intermolecular Interactions: σ-Hole Bonding. Australian Journal of Chemistry. https://doi.org/10.1071/ch10259

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.