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Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines
Open accessAbstract
A Cu(I)-catalyzed direct addition of alkynes to imines was developed. The process is simple and provides a diverse range of propargylamines in high enantiomeric excess and good yield both in water and in toluene. The absolute configuration of such addition products has been determined by x-ray crystallography.
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Citations
Cited by
The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups
Trost, B. M., & Weiss, A. H. (2009) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200800776 · Cited by 469
Chemoselectivity and the Curious Reactivity Preferences of Functional Groups
Afagh, N. A., & Yudin, A. K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200901317 · Cited by 320
Practical Alkoxythiocarbonyl Auxiliaries for Iridium(I)‐Catalyzed C−H Alkylation of Azacycles
Tran, A. T., & Yu, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704755 · Cited by 105
Metadata
- Authors
- Wei, C., Mague, J. T., & Li, C.-J.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2004-04-05
- Volume
- 101
- Issue
- 16
- Pages
- 5749-5754
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W1834418587
- Cited by
- 203
- References
- 0
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines. https://app.cochat.ai/papers/10.1073/pnas.0307150101
- The paper
- Wei, C., Mague, J. T., & Li, C.-J. (2004). Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.0307150101
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
