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Symmetry breaking in individual plasmonic nanoparticles

Open access
Wang, Hui, Wu, Yanpeng, Lassiter, Britt, Nehl, Colleen L., Hafner, Jason H., Nordlander, Peter, Halas, Naomi J.·2006·Proceedings of the National Academy of Sciences

Abstract

The plasmon resonances of a concentric metallic nanoshell arise from the hybridization of primitive plasmon modes of the same angular momentum on its inner and outer surfaces. For a nanoshell with an offset core, the reduction in symmetry relaxes these selection rules, allowing for an admixture of dipolar components in all plasmon modes of the particle. This metallodielectric nanostructure with reduced symmetry exhibits a core offset-dependent multipeaked spectrum, seen in single-particle spectroscopic measurements, and exhibits significantly larger local-field enhancements on its external surface than the equivalent concentric spherical nanostructure.

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Crossref · 10.1073/pnas.0604003103

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Metadata

Authors
Wang, H., Wu, Y., Lassiter, B., Nehl, C. L., Hafner, J. H., Nordlander, P., & Halas, N. J.
Venue
Proceedings of the National Academy of Sciences
Published
2006-07-18
Volume
103
Issue
29
Pages
10856-10860
ISSN
  • 0027-8424 (ISSN-L)
  • 1091-6490
OpenAlex
W2076178569
Cited by
296
References
1
FWCI
10.97
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Symmetry breaking in individual plasmonic nanoparticles. https://app.cochat.ai/papers/10.1073/pnas.0604003103
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Wang, H., Wu, Y., Lassiter, B., Nehl, C. L., Hafner, J. H., Nordlander, P., & Halas, N. J. (2006). Symmetry breaking in individual plasmonic nanoparticles. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.0604003103

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