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Partitioning of atmospherically relevant ions between bulk water and the water/vapor interface
Open accessAbstract
Recently, surface-sensitive spectroscopy data and molecular dynamics simulations have generated intense interest in the distribution of electrolyte ions between bulk water and the air/water interface. A partitioning model for cations and anions developed for biopolymer surface is extended here to interpret the effects of selected acids, bases, and salts on the surface tension of water. Data for electrolytes were analyzed by using a lower-bound value for the number of water molecules in the surface region [0.2 H 2 O Å −2 (approximately two layers of water)], obtained by assuming that both Na + and SO 4 2− (i.e., Na 2 SO 4 ) are fully excluded from this region. Surface–bulk partition coefficients of atmospherically relevant anions and the proton are determined. Notably, we find that H + is most strongly surface-accumulated, I − is modestly accumulated, NO 3 − is evenly distributed, and OH − is weakly excluded.
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Cites
Polarizability of the nitrate anion and its solvation at the air/water interface
Salvador, P., Curtis, J. E., Tobias, D. J., & Jungwirth, P. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b304537d · Cited by 143
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Water as an active constituent in cell biology
Ball, P. (2008) · Chemical Reviews · doi:10.1021/cr068037a · Cited by 2,177
Marx, D., Chandra, A., & Tuckerman, M. E. (2010) · Chemical Reviews · doi:10.1021/cr900233f · Cited by 522
Understanding specific ion effects and the Hofmeister series
Gregory, K. P., Elliott, G. R., Robertson, H., Kumar, A., Wanless, E. J., Webber, G. B., Craig, V. S. J., Andersson, G. G., & Page, A. J. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp00847e · Cited by 462
An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds
Kolb, C. E., Cox, R. A., Abbatt, J. P. D., Ammann, M., Davis, E. J., Donaldson, D. J., Garrett, B. C., George, C., Griffiths, P. T., Hanson, D. R., et al. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-10561-2010 · Cited by 405
Sasi, S., Rayaroth, M. P., Devadasan, D., Aravind, U. K., & Aravindakumar, C. T. (2015) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.06.072 · Cited by 72
Metadata
- Authors
- Pegram, L. M., & Record, M. T.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2006-09-26
- Volume
- 103
- Issue
- 39
- Pages
- 14278-14281
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W1992948302
- Cited by
- 174
- References
- 1
- FWCI
- 9.45
- Type
- journal article
- Language
- en
- Open access
- green
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- Pegram, L. M., & Record, M. T. (2006). Partitioning of atmospherically relevant ions between bulk water and the water/vapor interface. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.0606256103
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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