The DOI matches its Crossref record; 24 of the 27 references it cites were found in a registry or an index.
Metal-organic frameworks with high capacity and selectivity for harmful gases
Open accessAbstract
Benchmarks have been established for the performance of six metal-organic frameworks (MOFs) and isoreticular MOFs (IRMOFs, which have the same underlying topology as MOF-5), MOF-5, IRMOF-3, MOF-74, MOF-177, MOF-199, and IRMOF-62, as selective adsorbents for eight harmful gases: sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, and carbon monoxide. Kinetic breakthrough measurements are used to determine the calculated dynamic adsorption capacity of each “benchmark” MOF for each gas. The capacity of each MOF is compared to that of a sample of Calgon BPL activated carbon. We find that pore functionality plays a dominant role in determining the dynamic adsorption performance of MOFs. MOFs featuring reactive functionality outperform BPL carbon in all but one case and exhibit high dynamic adsorption capacities up to 35% by weight.
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“Hence, it is not surprising that most attention has been put on MOFs regarding this separation in the last years.574−577”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [577]
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Research works printed but not linked: 1
- D Tranchemontagne The Synthesis and Investigation of Alkyne-Containing Isoreticular Metal–Organic Frameworks for Hydrogen Storage and the Preliminary Investigation of Metal–Organic Frameworks for Gas Separation Applications. (Univ of California Los Angeles PhD thesis. (2007).
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Selective gas adsorption and separation in metal–organic frameworks
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Metadata
- Authors
- Britt, D., Tranchemontagne, D., & Yaghi, O. M.
- Affiliations
- California NanoSystems Institute (US)
- Venue
- Proceedings of the National Academy of Sciences
- Publisher
- National Academy of Sciences
- Published
- 2008-08-19
- Volume
- 105
- Issue
- 33
- Pages
- 11623-11627
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- PMC
- PMC2575308
- OpenAlex
- W2116516840
- Cited by
- 958
- References
- 27
- Citations by year
- 2026: 34 · 2025: 34 · 2024: 55 · 2023: 47 · 2022: 60 · 2021: 79 · 2020: 62 · 2019: 64 · 2018: 78 · 2017: 48 · 2016: 57 · 2015: 61 · 2014: 46 · 2013: 60 · 2012: 51
- FWCI
- 24.47
- Type
- journal article
- Language
- en
- Open access
- green
- www.ncbi.nlm.nih.gov
- Locations
- Proceedings of the National Academy of Sciences (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane Separation and Gas Transport
- Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
- Keywords
- metal-organic frameworks, isoreticular MOFs, gas adsorption, dynamic adsorption capacity, harmful gas removal, sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, carbon monoxide, MOF-5, MOF-74, MOF-177, HKUST-1, IRMOF-3, activated carbon comparison
- MeSH terms
- Gases, Kinetics, Metals, Models, Molecular, Organic Chemicals, Molecular Structure, Crystallography, X-Ray
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