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Extra-large pore zeolite (ITQ-40) with the lowest framework density containing double four- and double three-rings

Open access
Corma, A., Díaz-Cabañas, M. J., Jiang, J., Afeworki, M., Dorset, D. L., Soled, S. L., Strohmaier, K. G.·2010·Proceedings of the National Academy of Sciences

Abstract

The first zeolite structure (ITQ-40) that contains double four (D4) and double three (D3) member ring secondary building units has been synthesized by introducing Ge and NH 4 F and working in concentrated synthesis gels. It is the first time that D3-Rs have been observed in a zeolite structure. As was previously analyzed [Brunner GO, Meier, WM (1989) Nature 337:146–147], such a structure has a very low framework density (10.1 T/1,000 Å 3 ). Indeed, ITQ-40 has the lowest framework density ever achieved in oxygen-containing zeolites. Furthermore, it contains large pore openings, i.e., 15-member rings parallel to the [001] hexagonal axis and 16-member ring channels perpendicular to this axis. The results presented here push ahead the possibilities of zeolites for uses in electronics, control delivery of drugs and chemicals, as well as for catalysis.

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Metadata

Authors
Corma, A., Díaz-Cabañas, M. J., Jiang, J., Afeworki, M., Dorset, D. L., Soled, S. L., & Strohmaier, K. G.
Venue
Proceedings of the National Academy of Sciences
Published
2010-07-26
Volume
107
Issue
32
Pages
13997-14002
ISSN
  • 0027-8424 (ISSN-L)
  • 1091-6490
OpenAlex
W2069510631
Cited by
178
References
3
FWCI
9.32
Type
journal article
Language
en
Open access
green

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Corma, A., Díaz-Cabañas, M. J., Jiang, J., Afeworki, M., Dorset, D. L., Soled, S. L., & Strohmaier, K. G. (2010). Extra-large pore zeolite (ITQ-40) with the lowest framework density containing double four- and double three-rings. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1003009107

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