The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base
Open accessAbstract
Significance: Efficient and scalable catalysts that mediate the interconversion of electrical and chemical energy are essential to the future world economy. Central to this challenge are robust systems that can split water into its elements, hydrogen and oxygen, with minimal cost. In this article, we describe the discovery and characterization of an efficient, single-site homogeneous water oxidation catalyst based on a cationic cobalt-porphyrin system. Important roles of the buffer base in this catalysis are also described. Our results shed light on the design of next-generation water oxidation catalysts using earth-abundant transition metals and redox active ligand systems.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electrochemical methods, fundamentals and applications
Aikens, D. A. (1983) · Journal of Chemical Education · doi:10.1021/ed060pa25.1 · Cited by 3,139
Proton-Coupled Electron Transfer
Weinberg, D. R., Gagliardi, C. J., Hull, J. F., Murphy, C. F., Kent, C. A., Westlake, B. C., Paul, A., Ess, D. H., McCafferty, D. G., & Meyer, T. J. (2012) · Chemical Reviews · doi:10.1021/cr200177j · Cited by 2,421
Modern physical organic chemistry
(2006) · Choice Reviews Online · doi:10.5860/choice.43-3398 · Cited by 2,312
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Water-Splitting Chemistry of Photosystem II
McEvoy, J. P., & Brudvig, G. W. (2006) · Chemical Reviews · doi:10.1021/cr0204294 · Cited by 1,550
Artero, V., Chavarot‐Kerlidou, M., & Fontecave, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007987 · Cited by 1,393
Widegren, J. A., & Finke, R. G. (2003) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(02)00728-8 · Cited by 1,245
Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
Surendranath, Y., Kanan, M. W., & Nocera, D. G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106102b · Cited by 1,232
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s −1 for H 2 Production
Helm, M. L., Stewart, M. P., Bullock, R. M., DuBois, M. R., & DuBois, D. L. (2011) · Science · doi:10.1126/science.1205864 · Cited by 1,219
Cited by
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Molecular Catalysts for Water Oxidation
Blakemore, J. D., Crabtree, R. H., & Brudvig, G. W. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00122 · Cited by 1,150
Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins
Huang, X., & Groves, J. T. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00373 · Cited by 1,037
Self-citationArtificial photosynthesis: opportunities and challenges of molecular catalysts
Zhang, B., & Sun, L. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00897c · Cited by 954
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Liang, Z., Wang, H.-Y., Zheng, H., Zhang, W., & Cao, R. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01482f · Cited by 506
Metadata
- Authors
- Wang, D., & Groves, J. T.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2013-09-09
- Volume
- 110
- Issue
- 39
- Pages
- 15579-15584
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2033033166
- Cited by
- 397
- References
- 37
- FWCI
- 11.18
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base. https://app.cochat.ai/papers/10.1073/pnas.1315383110
- The paper
- Wang, D., & Groves, J. T. (2013). Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1315383110
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
