The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Graphene cover-promoted metal-catalyzed reactions
Open accessAbstract
Significance: Carbon deposits have been widely observed on metal surfaces in a variety of catalytic reactions, and the graphitic carbon species are often considered as inhibitors for surface reactions. We demonstrate here that CO adsorption and oxidation can occur on Pt surface covered by monolayer graphene, showing that the space between graphene overlayer and metal surface can act as a two-dimensional (2D) nanoreactor. Inside, CO oxidation happens with lower activation barrier due to the confinement effect of the graphene cover. This finding reminds us to reconsider the role of graphitic carbon in metal-catalyzed surface reactions and further provides a way to design novel catalysts.
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Cites
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
Wu, G., More, K. L., Johnston, C. M., & Zelenay, P. (2011) · Science · doi:10.1126/science.1200832 · Cited by 3,984
Cited by
Surface chemistry and catalysis confined under two-dimensional materials
Fu, Q., & Bao, X. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00424e · Cited by 532
Self-citationConfinement Catalysis with 2D Materials for Energy Conversion
Tang, L., Meng, X., Deng, D., & Bao, X. (2019) · Advanced Materials · doi:10.1002/adma.201901996 · Cited by 441
Self-citationWei, Z., Wang, J., Mao, S., Su, D., Jin, H., Wang, Y., Xu, F., Li, H., & Wang, Y. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00737 · Cited by 417
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Metadata
- Authors
- Yao, Y., Fu, Q., Zhang, Y. Y., Weng, X., Li, H., Chen, M., Jin, L., Dong, A., Mu, R., Jiang, P., Liu, L., Bluhm, H., Liu, Z., Zhang, S. B., & Bao, X.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2014-11-17
- Volume
- 111
- Issue
- 48
- Pages
- 17023-17028
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2077497579
- Cited by
- 211
- References
- 1
- FWCI
- 9.23
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Yao, Y., Fu, Q., Zhang, Y. Y., Weng, X., Li, H., Chen, M., Jin, L., Dong, A., Mu, R., Jiang, P., Liu, L., Bluhm, H., Liu, Z., Zhang, S. B., & Bao, X. (2014). Graphene cover-promoted metal-catalyzed reactions. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1416368111
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