The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films
Open accessAbstract
Significance: Iron-doped nickel oxide films are the most active nonnoble metal oxygen evolution reaction (OER) catalysts in alkaline electrolyte. Since Corrigan’s original discovery of enhanced activity with Fe doping in nickel oxides, the chemical basis for this synergy remains unclear. Recent studies suggest iron to assume a high valent oxidation state, thus promoting OER. We provide evidence for an alternative role of Fe 3+as a Lewis acid in the host nickel oxide. We observe that Fe 3+promotes the formation of Ni 4+, which leads to enhanced catalytic activity. This result is consistent with Fe 3+to be one of the strongest Lewis acidic metals by any measure of Lewis acidity, including hard–soft acid base theory, metal ion pK a s, and chemical inertness.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Hunter, B. M., Blakemore, J. D., Deimund, M., Gray, H. B., Winkler, J. R., & Müller, A. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja506087h · Cited by 321
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Xiao, Z., Huang, Y.-C., Dong, C.-L., Xie, C., Liu, Z., Du, S., Chen, W., Yan, D., Tao, L., Shu, Z., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00257 · Cited by 1,445
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
Kim, J. S., Kim, B., Kim, H., & Kang, K. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702774 · Cited by 940
Chen, R., Hung, S., Zhou, D., Gao, J., Yang, C., Tao, H., Yang, H. B., Zhang, L., Zhang, L., Xiong, Q., et al. (2019) · Advanced Materials · doi:10.1002/adma.201903909 · Cited by 624
Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives
Feng, C., Faheem, M. B., Fu, J., Xiao, Y., Li, C., & Li, Y. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05445 · Cited by 587
Metadata
- Authors
- Li, N., Bediako, D. K., Hadt, R. G., Hayes, D., Kempa, T. J., von Cube, F., Bell, D. C., Chen, L. X., & Nocera, D. G.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2017-01-30
- Volume
- 114
- Issue
- 7
- Pages
- 1486-1491
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2580932403
- Cited by
- 700
- References
- 3
- FWCI
- 16.22
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Li, N., Bediako, D. K., Hadt, R. G., Hayes, D., Kempa, T. J., von Cube, F., Bell, D. C., Chen, L. X., & Nocera, D. G. (2017). Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1620787114
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