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Assembly of silver Trigons into a buckyball-like Ag 180 nanocage
Open accessAbstract
Significance: Here we present a striking outcome from the alliance between chemistry and mathematics in the design, synthesis, and characterization of a silver cage, Ag 180 . In principle, the design replaces each carbon atom of C 60 with a triplet of argentophilicity-bonded silver atoms to produce a 3.4.6.4 (1,1) polyhedron with sixty 3-gons, ninety 4-gons, twelve 5-gons, and twenty 6-gons. Results from mass spectroscopy suggest an assembly mechanism in solution based on such triplets––the Silver-Trigon Assembly Road (STAR). Indeed, the STAR mechanism may be a general synthetic pathway toward even larger silver polyhedral cages. Besides its fundamental appeal, this synthetic cage may be considered for use as a molecular luminescent thermometer.
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Solving the structure of human H ferritin by genetically engineering intermolecular crystal contacts
Lawson, D. M., Artymiuk, P. J., Yewdall, S. J., Smith, J. M. A., Livingstone, J. C., Treffry, A., Luzzago, A., Levi, S., Arosio, P., Cesareni, G., et al. (1991) · Nature · doi:10.1038/349541a0 · Cited by 777
Cited by
Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency
Han, Z., Dong, X.-Y., Luo, P., Li, S., Wang, Z.-Y., Zang, S.-Q., & Mak, T. C. W. (2020) · Science Advances · doi:10.1126/sciadv.aay0107 · Cited by 298
Self-citationChemical Flexibility of Atomically Precise Metal Clusters
Li, S., Li, N.-N., Dong, X.-Y., Zang, S.-Q., & Mak, T. C. W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00896 · Cited by 280
Metadata
- Authors
- Wang, Z., Su, H.-F., Tan, Y.-Z., Schein, S., Lin, S.-C., Liu, W., Wang, S.-A., Wang, W.-G., Tung, C.-H., Sun, D., & Zheng, L.-S.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2017-10-27
- Volume
- 114
- Issue
- 46
- Pages
- 12132-12137
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2765181213
- Cited by
- 209
- References
- 1
- FWCI
- 13.44
- Type
- journal article
- Language
- en
- Open access
- green
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- Wang, Z., Su, H.-F., Tan, Y.-Z., Schein, S., Lin, S.-C., Liu, W., Wang, S.-A., Wang, W.-G., Tung, C.-H., Sun, D., & Zheng, L.-S. (2017). Assembly of silver Trigons into a buckyball-like Ag 180 nanocage. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1711972114
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