The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Global airborne sampling reveals a previously unobserved dimethyl sulfide oxidation mechanism in the marine atmosphere
Open accessAbstract
Dimethyl sulfide (DMS), emitted from the oceans, is the most abundant biological source of sulfur to the marine atmosphere. Atmospheric DMS is oxidized to condensable products that form secondary aerosols that affect Earth’s radiative balance by scattering solar radiation and serving as cloud condensation nuclei. We report the atmospheric discovery of a previously unquantified DMS oxidation product, hydroperoxymethyl thioformate (HPMTF, HOOCH 2 SCHO), identified through global-scale airborne observations that demonstrate it to be a major reservoir of marine sulfur. Observationally constrained model results show that more than 30% of oceanic DMS emitted to the atmosphere forms HPMTF. Coincident particle measurements suggest a strong link between HPMTF concentration and new particle formation and growth. Analyses of these observations show that HPMTF chemistry must be included in atmospheric models to improve representation of key linkages between the biogeochemistry of the ocean, marine aerosol formation and growth, and their combined effects on climate.
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Cites
Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 18
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Impact of nucleation on global CCN
Merikanto, J., Spracklen, D. V., Mann, G. W., Pickering, S. J., & Carslaw, K. S. (2009) · Atmospheric Chemistry and Physics · doi:10.5194/acp-9-8601-2009 · Cited by 851
Sulfur emissions to the atmosphere from natural sourees
Bates, T. S., Lamb, B. K., Guenther, A., Dignon, J., & Stoiber, R. E. (1992) · Journal of Atmospheric Chemistry · doi:10.1007/bf00115242 · Cited by 826
Marine aerosol production: a review of the current knowledge
O'Dowd, C. D., & de Leeuw, G. (2007) · Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2007.2043 · Cited by 729
Autoxidation of Organic Compounds in the Atmosphere
Crounse, J. D., Nielsen, L. B., Jørgensen, S., Kjaergaard, H. G., & Wennberg, P. O. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz4019207 · Cited by 726
Self-citationOcean-atmosphere interactions in the global biogeochemical sulfur cycle
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The case against climate regulation via oceanic phytoplankton sulphur emissions
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Bringing the ocean into the laboratory to probe the chemical complexity of sea spray aerosol
Prather, K. A., Bertram, T. H., Grassian, V. H., Deane, G. B., Stokes, M. D., DeMott, P. J., Aluwihare, L. I., Palenik, B. P., Azam, F., Seinfeld, J. H., et al. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1300262110 · Cited by 618
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Metadata
- Authors
- Veres, P. R., Neuman, J. A., Bertram, T. H., Assaf, E., Wolfe, G. M., Williamson, C. J., Weinzierl, B., Tilmes, S., Thompson, C. R., Thames, A. B., Schroder, J. C., Saiz-Lopez, A., Rollins, A. W., Roberts, J. M., Price, D., Peischl, J., Nault, B. A., Møller, K. H., Miller, D. O., Meinardi, S., Li, Q., Lamarque, J.-F., Kupc, A., Kjaergaard, H. G., Kinnison, D., Jimenez, J. L., Jernigan, C. M., Hornbrook, R. S., Hills, A., Dollner, M., Day, D. A., Cuevas, C. A., Campuzano-Jost, P., Burkholder, J., Bui, T. P., Brune, W. H., Brown, S. S., Brock, C. A., Bourgeois, I., Blake, D. R., Apel, E. C., & Ryerson, T. B.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2020-02-18
- Volume
- 117
- Issue
- 9
- Pages
- 4505-4510
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W3007487957
- Cited by
- 328
- References
- 29
- FWCI
- 17.30
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Veres, P. R., Neuman, J. A., Bertram, T. H., Assaf, E., Wolfe, G. M., Williamson, C. J., Weinzierl, B., Tilmes, S., Thompson, C. R., Thames, A. B., Schroder, J. C., Saiz-Lopez, A., Rollins, A. W., Roberts, J. M., Price, D., Peischl, J., Nault, B. A., Møller, K. H., Miller, D. O., . . . Ryerson, T. B. (2020). Global airborne sampling reveals a previously unobserved dimethyl sulfide oxidation mechanism in the marine atmosphere. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1919344117
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