Electronic properties of intercalation complexes of the transition metal dichalcogenides

Abstract

Intercalation of the layer type transition metal dichalcogenides by a variety of organic molecules, alkali metals, or ‘3d’ transition metals, provides a powerful way to finely tune the electron occupation of the relatively narrow ‘d’ bands met in these solids. These transition metal dichalcogenides are highly anisotropic solids, sometimes referred to as ‘two-dimensional’ solids, and the intercalant molecules which are electron donors enter between the layers. This can result in profound changes in the electronic properties of the host lattice, and these changes can be understood in terms of charge transfer and increased interlayer separation. The phenomena discussed include optical properties, transport properties, super-conductivity, order-disorder phenomena and phase changes, staging, magnetic properties, metal-insulator transitions, Anderson localization, and fast-ion conduction. Some possible practical applications are also considered.