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On the mechanism of specific phosphate adsorption by hydroxylated mineral surfaces: A review
Abstract
The mechanism of specific phosphate adsorption by hydroxy‐lated mineral surfaces comprises two aspects: the phosphate‐hydroxyl surface reaction and the configuration of the adsorbed phosphate ion. Evidence pointing to ligand exchange as the mechanism of the phosphate‐surface hydroxyl reaction include kinetics of adsorption and desorption; hydroxyl ion release; infrared spectroscopy, and stereochemical calculations. Data pertaining to the coordination of adsorbed phosphate on hydroxy‐lated mineral surfaces have not been conclusive overall. Isotopic exchange experiments and studies of desorption kinetics do not provide definitive information on surface coordination. Measurements of hydroxyl ion release and crystallographic calculations provide support for the existence of both monodentate and bidentate surface complexes of phosphate ions. Infrared spectroscopic investigations suggest a binuclear complex on dried, phosphated goethite. However, these studies cannot be extrapolated automatically to soil minerals, since the addition of water favors formation of a monodentate surface complex. Further research is needed to establish the configuration of adsorbed phosphate ions.
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Citations
Cited by
Arai, Y., & Sparks, D. L. (2001) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2001.7773 · Cited by 757
Wilfert, P., Kumar, P. S., Korving, L., Witkamp, G.-J., & van Loosdrecht, M. C. M. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b00150 · Cited by 607
Adsorption of selenium by amorphous iron oxyhydroxide and manganese dioxide
Balistrieri, L. S., & Chao, T. T. (1990) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(90)90369-v · Cited by 386
Assessment of gross and net mineralization rates of soil organic phosphorus – A review
Bünemann, E. K. (2015) · Soil Biology and Biochemistry · doi:10.1016/j.soilbio.2015.06.026 · Cited by 345
Fixen, P. E., & Grove, J. H. (1990) · SSSA Book Series · doi:10.2136/sssabookser3.3ed.c7 · Cited by 313
Metadata
- Authors
- Goldberg, S., & Sposito, G.
- Venue
- Communications in Soil Science and Plant Analysis
- Publisher
- Informa UK Limited
- Published
- 1985-08
- Volume
- 16
- Issue
- 8
- Pages
- 801-821
- ISSN
- 0010-3624 (ISSN-L)
- 1532-2416
- OpenAlex
- W2032202194
- Cited by
- 227
- References
- 0
- FWCI
- 5.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Goldberg, S., & Sposito, G. (1985). On the mechanism of specific phosphate adsorption by hydroxylated mineral surfaces: A review. Communications in Soil Science and Plant Analysis. https://doi.org/10.1080/00103628509367646
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