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Ultracold molecules and ultracold chemistry
Abstract
The recent development of a range of new methods for producing samples of gas-phase molecules that are translationally cold ( K) or ultracold ( mK) is driving efforts to study reactive and inelastic collisional processes in these temperature regimes. In this review article the new methods for cold/ultracold molecule production are reviewed in the context of their potential or current use in collisional studies and progress in the application of these methods is highlighted. In these sub-Kelvin temperature ranges, where the de Broglie wavelength is long compared with molecular dimensions, quantum effects may play a crucial role in the collision dynamics. Reactions with no potential energy barrier are of greatest importance, and this review article summarizes some of the principal theoretical approaches to understanding quantum effects in these barrierless processes.
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Cites
Current Status of Transition-State Theory
Truhlar, D. G., Garrett, B. C., & Klippenstein, S. J. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp953748q · Cited by 2,279
Fast Quantum Gates for Neutral Atoms
Jaksch, D., Cirac, J. I., Zoller, P., Rolston, S. L., Côté, R., & Lukin, M. D. (2000) · Physical Review Letters · doi:10.1103/physrevlett.85.2208 · Cited by 1,540
Cited by
Reversing hydride-ion formation in quantum-information experiments with Be +
Sawyer, B. C., Bohnet, J. G., Britton, J. W., & Bollinger, J. J. (2015) · Physical Review A · doi:10.1103/physreva.91.011401 · Cited by 27
Metadata
- Authors
- Bell, M. T., & P. Softley, T.
- Venue
- Molecular Physics
- Publisher
- Informa UK Limited
- Published
- 2009-01-20
- Volume
- 107
- Issue
- 2
- Pages
- 99-132
- ISSN
- 0026-8976 (ISSN-L)
- 1362-3028
- OpenAlex
- W2124105223
- Cited by
- 276
- References
- 2
- FWCI
- 14.13
- Type
- journal article
- Language
- en
- Open access
- closed
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