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Simplification of the molecular vibration-rotation hamiltonian
Abstract
By use of the commutation relations and sum rules, the Darling-Dennison vibration-rotation hamiltonian for a non-linear molecule is rearranged to the form: The order of the factors in the first term is immaterial, on account of the relation: A simple expansion is given for the μαβ tensor in terms of the normal coordinates.
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Citations
Cited by
The HITRAN2016 molecular spectroscopic database
Gordon, I. E., Rothman, L. S., Hill, C., Kochanov, R. V., Tan, Y., Bernath, P. F., Birk, M., Boudon, V., Campargue, A., Chance, K. V., et al. (2017) · Journal of Quantitative Spectroscopy and Radiative Transfer · doi:10.1016/j.jqsrt.2017.06.038 · Cited by 7,721
The HITRAN2020 molecular spectroscopic database
Gordon, I. E., Rothman, L. S., Hargreaves, R. J., Hashemi, R., Karlovets, E. V., Skinner, F. M., Conway, E. K., Hill, C., Kochanov, R. V., Tan, Y., et al. (2022) · Journal of Quantitative Spectroscopy and Radiative Transfer · doi:10.1016/j.jqsrt.2021.107949 · Cited by 2,600
Reaction path Hamiltonian for polyatomic molecules
Miller, W. H., Handy, N. C., & Adams, J. E. (1980) · The Journal of Chemical Physics · doi:10.1063/1.438959 · Cited by 1,430
Anharmonic force constant calculations
Hoy, A. R., Mills, I. M., & Strey, G. (1972) · Molecular Physics · doi:10.1080/00268977200102361 · Cited by 955
AFGL atmospheric absorption line parameters compilation: 1982 edition
Rothman, L. S., Gamache, R. R., Barbe, A., Goldman, A., Gillis, J. R., Brown, L. R., Toth, R. A., Flaud, J.-M., & Camy-Peyret, C. (1983) · Applied Optics · doi:10.1364/ao.22.002247 · Cited by 447
Metadata
- Authors
- Watson, J. K. G.
- Venue
- Molecular Physics
- Publisher
- Informa UK Limited
- Published
- 1968-01
- Volume
- 15
- Issue
- 5
- Pages
- 479-490
- ISSN
- 0026-8976 (ISSN-L)
- 1362-3028
- OpenAlex
- W2070089774
- Cited by
- 1,142
- References
- 0
- FWCI
- 4.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Watson, J. K. G. (1968). Simplification of the molecular vibration-rotation hamiltonian. Molecular Physics. https://doi.org/10.1080/00268976800101381
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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