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Studies of chemical exchange by nuclear magnetic relaxation in the rotating frame
Abstract
The exchange of protons between sites with different chemical shift is studied by means of N.M.R. relaxation time measurements (T 1ρ ) in the presence of an r.f. magnetic field. The system studied is chair-to-chair isomerization in cyclohexane. The exchange rate and chemical shift are measured in the temperature range 215°k to 250°k. The method is compared with other N.M.R. techniques for studying chemical exchange and is found to have advantages particularly at high exchange rates.
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Citations
Cited by
Palmer, A. G., Kroenke, C. D., & Patrick Loria, J. (2001) · Methods in Enzymology · doi:10.1016/s0076-6879(01)39315-1 · Cited by 938
Campbell, D. M., Mackowiak, M., & Jonas, J. (1992) · The Journal of Chemical Physics · doi:10.1063/1.462019 · Cited by 275
Brath, U., & Akke, M. (2009) · Journal of Molecular Biology · doi:10.1016/j.jmb.2009.01.047 · Cited by 36
Metadata
- Authors
- Deverell, C., Morgan, R. E., & Strange, J. H.
- Venue
- Molecular Physics
- Publisher
- Informa UK Limited
- Published
- 1970-04
- Volume
- 18
- Issue
- 4
- Pages
- 553-559
- ISSN
- 0026-8976 (ISSN-L)
- 1362-3028
- OpenAlex
- W2018736034
- Cited by
- 268
- References
- 0
- FWCI
- 1.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Studies of chemical exchange by nuclear magnetic relaxation in the rotating frame. https://app.cochat.ai/papers/10.1080/00268977000100611
- The paper
- Deverell, C., Morgan, R. E., & Strange, J. H. (1970). Studies of chemical exchange by nuclear magnetic relaxation in the rotating frame. Molecular Physics. https://doi.org/10.1080/00268977000100611
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
