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Hydrogen bonds in water: Network organization and lifetimes
Abstract
Equilibrium and dynamical properties of the hydrogen bonds in liquid water are analysed using the results of molecular dynamics simulations of the MCY-CI model. Properties of the hydrogen bond clusters as functions of temperature are described. The connectivity of the clusters is analysed in terms of the bridgeless polygons which are formed by the bonds. The problem of obtaining a meaningful definition of bond lifetime is discussed, and the results of lifetime measurements based on alternative definitions are shown.
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Citations
Cited by
On the Molecular Mechanism of Water Reorientation
Laage, D., & Hynes, J. T. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp805217u · Cited by 438
Zhao, W., Leroy, F., Heggen, B., Zahn, S., Kirchner, B., Balasubramanian, S., & Müller-Plathe, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906337p · Cited by 313
Structure, Dynamics, and Spectral Diffusion of Water from First-Principles Molecular Dynamics
Bankura, A., Karmakar, A., Carnevale, V., Chandra, A., & Klein, M. L. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp506120t · Cited by 166
Metadata
- Authors
- Rapaport, D. C.
- Venue
- Molecular Physics
- Publisher
- Informa UK Limited
- Published
- 1983-12-10
- Volume
- 50
- Issue
- 5
- Pages
- 1151-1162
- ISSN
- 0026-8976 (ISSN-L)
- 1362-3028
- OpenAlex
- W2109671158
- Cited by
- 629
- References
- 0
- FWCI
- 1.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Hydrogen bonds in water: Network organization and lifetimes. https://app.cochat.ai/papers/10.1080/00268978300102931
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- Rapaport, D. C. (1983). Hydrogen bonds in water: Network organization and lifetimes. Molecular Physics. https://doi.org/10.1080/00268978300102931
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
