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Cited by 20Industrial Gas Emission ControlCarbon Dioxide Capture TechnologiesZeolite Catalysis and Synthesis

The DOI matches its Crossref record.

DYNAMIC ADSORPTION OF S02 ON ZEOLITE MOLECULAR SIEVES†

KOPAQ∗, TURKAN, KAYMAKgi, ERDOGAN, KOPAC, MEHMET·1998·Chemical Engineering Communications
DOI 10.1080/00986449808912360
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Abstract

Sulfur dioxide is one of the major pollutants resulting from fuel combustion. Numerous dry, semi-dry and wet processes have been developed for pollution control of sulfur dioxide. Solid carbonates, natural and synthetic zeolites, ion exchange resins and carbon based sorbents are the most commonly used dry sorbents for sulfur dioxide removal In this study, measurements of the adsorption properties of sulfur dioxide on zeolites were investigated. The adsorbents used in this work are 5A, 4A and AW300 type molecular sieve zeolites. Adsorption equilibrium parameters were determined from the pulse chromatographic response to injections of low concentrations of sulfur dioxide. The method of moments were used to evaluate the adsorption equilibrium parameters from pulse chromatographic experiments. Data, such as adsorption equilibrium constants or reaction rate parameters are essential in the design of adsorption systems or reactors in which sulfur dioxide is removed The experiments were conducted in a temperature range of 523-718 K. The relatively strong adsorption properties of sulfur dioxide on zeolites necessitated the use of high carrier gas flow rates and subsequently non-isobaric operation. Non-isobaric pulse chromatography theory was found to describe accurately the adsorption trends." printpubdate="Adsorption equilibrium constants of S02 were found to decrease considerably with increasing temperature. It was also found out that adsorption of SO2 on the adsorbents investigated were found to decrease in the order of AW300  4A  5A. The adsorption equilibrium parameter of S02 on 5A was found as 11.78 at 673 K, whereas it has a value of 157.11 at 523 K. The adsorption equilibrium parameter of S02 on 4A zeolite was determined to be 8.63 at 718 K and 213.78 at 523 K.

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Research works printed but not linked: 18

  1. Alpay E., 1994, Chem. Eng. Sci., 49, 5845, 10.1016/0009-2509(94)00353-X · DOI
  2. Alpay E., 1996, Gas Sep. Purif., 10, 25, 10.1016/0950-4214(96)00002-3 · DOI
  3. Breck D. W., 1974, Zeolite Molecular Sieves,
  4. Carleton F. B., 1978, Chem. Eng. Sci., 33, 1239, 10.1016/0009-2509(78)85089-1 · DOI
  5. Dogu G., 1976, Chem. Eng. Sci., 31, 123, 10.1016/0009-2509(76)85047-6 · DOI
  6. Dogu G., 1978, AIChE J, 21, 58, 10.1002/aic.690210106 · DOI
  7. 10.1002/cjce.5450610507 · DOI
  8. Dogu G., 1988, Can. J. Chem. Eng., 66, 605, 10.1002/cjce.5450660411 · DOI
  9. 10.1002/aic.690350816 · DOI
  10. Ruthven D. M., 1984, Principles of Adsorption and Adsorption Processes,
  11. 10.1002/aic.690140516 · DOI
  12. 10.1002/aic.690140613 · DOI
  13. 10.1021/i160047a014 · DOI
  14. 10.1021/i160050a005 · DOI
  15. 10.1016/0009-2509(75)80062-5 · DOI
  16. Haynes H. W. Jr., 1973, AIChE J., 19, 1043, 10.1002/aic.690190526 · DOI
  17. 10.1002/aic.690270113 · DOI
  18. Kopac T., 1996, Chem. Eng. Sci., 51, 2201, 10.1016/0009-2509(96)00077-2 · DOI

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Metadata

Authors
KOPAQ∗, T., KAYMAKgi, E., & KOPAC, M.
Affiliations
  • a Department of Chemistry , Zonguldak Karaelmas University , Zonguldak, 67100, Turkey
  • Zonguldak Bülent Ecevit University (TR)
Venue
Chemical Engineering Communications
Publisher
Informa UK Limited
Published
1998-01
Volume
164
Issue
1
Pages
99-109
ISSN
  • 0098-6445 (ISSN-L)
  • 1563-5201
DOI
10.1080/00986449808912360
OpenAlex
W2040824120
Cited by
20
References
0
Citations by year
2026: 1 · 2025: 1 · 2022: 2 · 2020: 1 · 2019: 1 · 2015: 1 · 2014: 1 · 2013: 1
FWCI
3.84
Type
journal article
Language
en
Open access
closed
Locations
  • Chemical Engineering Communications (publishedVersion)
  • Zonguldak Bülent Ecevit University Institutional Repository (submittedVersion)
Topics
  • Physical Sciences › Environmental Science › Environmental Engineering › Industrial Gas Emission Control
  • Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
  • Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
Keywords
SO2 adsorption, zeolite molecular sieves, SO2 removal, adsorption equilibrium constant, method of moments, temperature effect on adsorption, zeolite 5A, zeolite A, flue gas desulfurization

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