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Chiral nematic suspensions of cellulose crystallites; phase separation and magnetic field orientation
Abstract
Suspensions of rod-like cellulose crystallites of axial ratio ≈ 20–40, prepared by acid hydrolysis of natural cellulose fibres with sulphuric acid, give stable ordered fluids that display well-formed textures and disclinations characteristic of chiral nematic liquid crystalline phases. The critical volume fraction for phase separation of salt-free suspensions is typically 0.03, with a relatively narrow biphasic region. Because of the negative diamagnetic susceptibility of cellulose, the ordered phase becomes oriented in a magnetic field with its chiral nematic axis parallel to the applied field.
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Citations
Cited by
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980
Azizi Samir, M. A. S., Alloin, F., & Dufresne, A. (2005) · Biomacromolecules · doi:10.1021/bm0493685 · Cited by 2,311
Beck-Candanedo, S., Roman, M., & Gray, D. G. (2005) · Biomacromolecules · doi:10.1021/bm049300p · Cited by 1,588
Self-citationEffect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose
DONG, X. M., REVOL, J.-F., & GRAY, D. G. (1998) · Cellulose · doi:10.1023/a:1009260511939 · Cited by 1,032
Self-citationRodlike cellulose microcrystals: Structure, properties and applications
de Souza Lima, M. M., & Borsali, R. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200300268 · Cited by 894
Metadata
- Authors
- Revol, J.-F., Godbout, L., Dong, X.-M., Gray, D. G., Chanzy, H., & Maret, G.
- Venue
- Liquid Crystals
- Publisher
- Informa UK Limited
- Published
- 1994-01
- Volume
- 16
- Issue
- 1
- Pages
- 127-134
- ISSN
- 0267-8292 (ISSN-L)
- 1366-5855
- OpenAlex
- W2014042403
- Cited by
- 464
- References
- 0
- FWCI
- 2.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Revol, J.-F., Godbout, L., Dong, X.-M., Gray, D. G., Chanzy, H., & Maret, G. (1994). Chiral nematic suspensions of cellulose crystallites; phase separation and magnetic field orientation. Liquid Crystals. https://doi.org/10.1080/02678299408036525
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