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Kraft Lignin-Based Rigid Polyurethane Foam

Li, Yang, Ragauskas, Arthur J.·2012·Journal of Wood Chemistry and Technology

Abstract

Kraft pine lignin was derivatized to a liquid polyol through oxypropylation. The resulting polyol was characterized by GPC, FT-IR, H1, C13, and P31 NMR and was compared to commercial polyols in view of the mechanical property of the corresponding rigid polyurethane foams for the first time. A series of lignin-based PU was synthesized by replacing varying weight percentages of the amount of sucrose polyol and glycerol polyol, two commonly used commercial polyols employed in the control foam preparation. All foams had a low density of ∼30 Kg m−3 and showed typical linkages of PU in the FT-IR spectra. The diameter of closed-cells was ∼650 μm for most of the foams as revealed by SEM images. The optimal compressive property of rigid PU foams was obtained using lignin polyol without the addition of any other commercial polyols primarily attributed to the rigidity of lignin aromatic structure and the high functionality of lignin hydroxyl groups.

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Metadata

Authors
Li, Y., & Ragauskas, A. J.
Venue
Journal of Wood Chemistry and Technology
Published
2012-07
Volume
32
Issue
3
Pages
210-224
ISSN
  • 0277-3813 (ISSN-L)
  • 1532-2319
OpenAlex
W2089024863
Cited by
223
References
3
FWCI
8.37
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Kraft Lignin-Based Rigid Polyurethane Foam. https://app.cochat.ai/papers/10.1080/02773813.2011.652795
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Li, Y., & Ragauskas, A. J. (2012). Kraft Lignin-Based Rigid Polyurethane Foam. Journal of Wood Chemistry and Technology. https://doi.org/10.1080/02773813.2011.652795

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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