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Cited by 161

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Method for the Determination of Three Toxic Non-Ortho chlorine Substituted Coplanar PCBs in Environmental Samples at Part-per-Trillion Levels

Tanabe, Shinsuke, Kannan, Narayanan, Wakimoto, Tadaaki, Tatsukawa, Ryo·1987·International Journal of Environmental Analytical Chemistry

Abstract

A method has been devised combining alkali digestion, carbon chromatography and high-resolution gas chromatography for the determination of 3,3',4,4'-tetra, 3,3',4,4',5-penta, and 3,3',4,4',5,5'-hexachlorobiphenyl, the biologically active congeners of PCBs and approximate isostereomers of 2,3,7,8-TCDD. This method permits determinations of parts-per-trillion levels of these toxic residues in biological samples. Interference both from biogenic and from xenobiotic substances was reduced to extremely low levels. Using this method, 13.5 ng of 3,3'4,4'-tetrachlorobiphenyl/g, 0.89 ng of 3,3'4,4',5-pentachlorobiphenyl/g and 0.64 ng of 3,3',4,4'5,5'-hexachlorobiphenyl/g were detected on wet weight basis in the blubber of a finless porpoise. To our knowledge this is the first report on the three toxic non-ortho chlorine substituted PCB residues detected in a higher mammal in the wilderness.

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Metadata

Authors
Tanabe, S., Kannan, N., Wakimoto, T., & Tatsukawa, R.
Venue
International Journal of Environmental Analytical Chemistry
Published
1987-04
Volume
29
Issue
3
Pages
199-213
ISSN
  • 0306-7319 (ISSN-L)
  • 1029-0397
OpenAlex
W2086630460
Cited by
161
References
0
FWCI
11.11
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Method for the Determination of Three Toxic Non-Ortho chlorine Substituted Coplanar PCBs in Environmental Samples at Part-per-Trillion Levels. https://app.cochat.ai/papers/10.1080/03067318708079836
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Tanabe, S., Kannan, N., Wakimoto, T., & Tatsukawa, R. (1987). Method for the Determination of Three Toxic Non-Ortho chlorine Substituted Coplanar PCBs in Environmental Samples at Part-per-Trillion Levels. International Journal of Environmental Analytical Chemistry. https://doi.org/10.1080/03067318708079836

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.