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A REVIEW OF THE BASIC CHEMISTRY AND RECENT DEVELOPMENTS IN TRIVALENT f-ELEMENTS SEPARATIONS
Abstract
Among the most difficult of separations of metal ions are the intra- and intergroup separation of Ianthanides and trivalent actinides. Yet environmental concerns related to radioactivity, and new high-tech developments which have increased the demand for pure lanthanides have combined to foster a greater need for effective procedures to attain these separations. The most recent review which concentrated on this problem is now nearly 20 years old. While the methods developed over the preceeding 50-60 years of research are still in use, new understanding and some promising new methods are currently under development. The present manuscript is partly a tutorial of the basic chemical principles leading to successful separations, and partly a review of the results of the past 10-12 years on the separation of trivalent lanthanides and actinides, both intra-, and intergroup.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
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Cited by
Review on hydrometallurgical recovery of rare earth metals
Jha, M. K., Kumari, A., Panda, R., Rajesh Kumar, J., Yoo, K., & Lee, J. Y. (2016) · Hydrometallurgy · doi:10.1016/j.hydromet.2016.01.035 · Cited by 688
Ligands for f-element extraction used in the nuclear fuel cycle
Leoncini, A., Huskens, J., & Verboom, W. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00574a · Cited by 486
Separation of Rare Earths by Solvent Extraction
THAKUR, N. V. (2000) · Mineral Processing and Extractive Metallurgy Review · doi:10.1080/08827500008914171 · Cited by 90
Sole, K. (2008) · Solvent Extraction and Liquid Membranes · doi:10.1201/9781420014112.ch5 · Cited by 35
Sehati, N., Shiri-Yekta, Z., Zamani, A. A., Yaftian, M. R., & Noshiranzadeh, N. (2012) · Separation Science and Technology · doi:10.1080/01496395.2011.629399 · Cited by 11
Metadata
- Authors
- Nash, K. L.
- Venue
- Solvent Extraction and Ion Exchange
- Publisher
- Informa UK Limited
- Published
- 1993-05
- Volume
- 11
- Issue
- 4
- Pages
- 729-768
- ISSN
- 0736-6299 (ISSN-L)
- 1532-2262
- OpenAlex
- W1970368702
- Cited by
- 526
- References
- 2
- FWCI
- 4.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nash, K. L. (1993). A REVIEW OF THE BASIC CHEMISTRY AND RECENT DEVELOPMENTS IN TRIVALENT f-ELEMENTS SEPARATIONS. Solvent Extraction and Ion Exchange. https://doi.org/10.1080/07366299308918184
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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