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Metal ions binding onto lignocellulosic biosorbent
Abstract
This paper describes the use of a lignocellulosic biosorbent for the adsorption and ion exchange of nine different heavy metals ions. Batch isothermal equilibrium and continuous column adsorption experiments were carried out in an effort to evaluate the maximum adsorption capacity, pH dependence and to study the mechanism of removal of metal ions onto the biosorbent. Bio-sorption data were interpreted using Langmuir isotherm which reflect the influence of metal concentration on the uptake of the metal ion. Potentiometric titrations were used to determine the contents of total functional groups. The biosorbent showed the strongest affinity for Pb2+, Hg2+ and Cu2+. The metal ions such as Cd2+, Cu2+, Ni2+, Co2+, and Mn2+ seemed to be exclusively involved in ion-exchange mechanism with Ca2+ ions. The column adsorption experiment of multiple metals revealed the role of another cation in effective removal of Pb2+, Hg2+ and Zn2+. The biosorbent has been found to be a good electron donor for the reduction of Cr(VI) in an acidic medium.
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“Ionic carboxylic functional groups (COO-) were involved in Cr(VI) sorption at peaks 1285, 1541, 1650 cm À1 for unloaded TWB and at 1353, 1408, 1612 cm À1 for Cr(VI) loaded TWB [67].”
From Adsorption-reduction performance of tea waste and rice husk biochars for Cr(VI) elimination from wastewater (2020) · cites this paper as [67]
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Khalil, U., Bilal Shakoor, M., Ali, S., Rizwan, M., Nasser Alyemeni, M., & Wijaya, L. (2020) · Journal of Saudi Chemical Society · doi:10.1016/j.jscs.2020.07.001 · Cited by 139
“Ionic carboxylic functional groups (COO–) were involved in Cr(VI) sorption at peaks 1285, 1541, 1650 cm (cid:1) 1 for unloaded TWB and at 1353, 1408, 1612 cm (cid:1) 1 for Cr(VI) loaded TWB [67].”
Metadata
- Authors
- Krishnani, K. K., Meng, X., & Dupont, L.
- Affiliations
- Central Institute of Brackishwater Aquaculture (IN)
- Stevens Institute of Technology (US)
- Université de Reims Champagne-Ardenne (FR)
- Venue
- Journal of Environmental Science and Health Part A
- Publisher
- Informa UK Limited
- Published
- 2009-05
- Volume
- 44
- Issue
- 7
- Pages
- 688-699
- ISSN
- 1093-4529 (ISSN-L)
- 1532-4117
- OpenAlex
- W1963878648
- Cited by
- 48
- References
- 48
- Citations by year
- 2026: 2 · 2025: 5 · 2024: 1 · 2023: 3 · 2022: 3 · 2021: 2 · 2020: 2 · 2019: 3 · 2018: 1 · 2017: 3 · 2016: 4 · 2015: 7 · 2013: 4 · 2012: 3
- FWCI
- 2.75
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Environmental Science and Health Part A (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Water Science and Technology › Heavy Metal Pollution Remediation
- Keywords
- lignocellulosic biosorbent, heavy metal adsorption, ion exchange, lead, mercury, copper, cadmium, nickel, cobalt, manganese, zinc, hexavalent chromium reduction, Langmuir isotherm, potentiometric titration, functional groups, column adsorption, pH dependence, metal removal
- MeSH terms
- Adsorption, Cations, Divalent, Cellulose, Hydrogen-Ion Concentration, Lignin, Metals, Models, Theoretical
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