The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
XCV. Symmetry changes in barium titanate at low temperatures and their relation to its ferroelectric properties
Abstract
Summary The optical changes in BaTiO3 are described, and it is shown that they can be completely explained if the crystal symmetry changes from tetragonal to orthorhombic at -5°C, and then to rhombohedral at -90°C. These changes have been confirmed by X-ray investigations, and it is concluded that the three transitions are caused by the structure becoming successively spontaneously polarized along the [100] [110] and [111] cube directions. The relation of polarization to the cell structure is discussed and it is shown that the simple Lorentz equation is inapplicable if the titanium-oxygen interaction energy is large. An explanation of the three transitions is outlined on the basis of this interaction and some difficulties of electrical dipole cooperative effects in BaTiO3 are discussed.
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Citations
Cites
Electronic Processes in Ionic Crystals
Mott, N. F., & Gurney, R. W. (1940) · CERN Document Server (European Organization for Nuclear Research) · Cited by 2,487
Fröhlich, H., & Maradudin, A. A. (1949) · CERN Document Server (European Organization for Nuclear Research) · Cited by 2,213
Statistical theory of superlattices
Bethe, H. A. (1935) · Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences · doi:10.1098/rspa.1935.0122 · Cited by 1,069
Statistical Theory of Superlattices
Bethe, H. A. (1997) · World Scientific Series in 20th Century Physics · doi:10.1142/9789812795755_0010 · Cited by 740
Polarisability and dielectric constant of ionic crystals
Szigeti, B. (1949) · Transactions of the Faraday Society · doi:10.1039/tf9494500155 · Cited by 491
Dielectric and Piezoelectric Properties of Barium Titanate
Roberts, S. (1947) · Physical Review · doi:10.1103/physrev.71.890 · Cited by 309
Theoretical Model for Explaining the Ferroelectric Effect in Barium Titanate
Mason, W. P., & Matthias, B. T. (1948) · Physical Review · doi:10.1103/physrev.74.1622 · Cited by 119
Cited by
BaTiO3-Based Piezoelectrics: Fundamentals, Current Status, and Perspectives
Acosta, M., Novak, N., Rojas, V., Patel, S., Vaish, R., Koruza, J., Rossetti, G. A., & Rödel, J. (2017) · Applied Physics Reviews · doi:10.1063/1.4990046 · Cited by 1,451
Electric-field control of magnetic order above room temperature
Cherifi, R. O., Ivanovskaya, V., Phillips, L. C., Zobelli, A., Infante, I. C., Jacquet, E., Garcia, V., Fusil, S., Briddon, P. R., Guiblin, N., et al. (2014) · Nature Materials · doi:10.1038/nmat3870 · Cited by 549
An integrated optical modulator operating at cryogenic temperatures
Eltes, F., Villarreal-Garcia, G. E., Caimi, D., Siegwart, H., Gentile, A. A., Hart, A., Stark, P., Marshall, G. D., Thompson, M. G., Barreto, J., et al. (2020) · Nature Materials · doi:10.1038/s41563-020-0725-5 · Cited by 182
Metadata
- Authors
- Kay, H. F., & Vousden, P.
- Venue
- The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
- Publisher
- Informa UK Limited
- Published
- 1949-10
- Volume
- 40
- Issue
- 309
- Pages
- 1019-1040
- ISSN
- 1941-5982 (ISSN-L)
- 1941-5990
- OpenAlex
- W1988257566
- Cited by
- 507
- References
- 7
- FWCI
- 7.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kay, H. F., & Vousden, P. (1949). XCV. Symmetry changes in barium titanate at low temperatures and their relation to its ferroelectric properties. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. https://doi.org/10.1080/14786444908561371
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