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MICROPOROUS INORGANIC MEMBRANES
Abstract
Recent development in microporous inorganic membranes represents a significant advance in materials for separation and chemical reaction applications. This paper provides an in-depth review of synthesis and properties of two groups (amorphous and crystalline) of microporous inorganic membranes. Amorphous microporous silica membranes can be prepared by the sol-gel and phase separation methods. Flat sheet, tubular and hollow fiber amorphous carbon membranes have been fabricated by various pyrolysis methods from polymer precursors. A large number of synthesis methods have been developed to prepare good quality polycrystalline zeolite membranes. Several techniques, including vapor and liquid approaches, are reviewed for pore structure modification to prepare microporous inorganic membranes from mesoporous inorganic membranes. Chemical, microstructural and permeation properties of these microporous membranes are summarized and compared among the several microporous membranes discussed in this paper. Theory for gas permeation through microporous membranes is also reviewed, with emphasis on comparison of theoretical with the experimental data. These inorganic microporous membranes offer excellent separation properties by the mechanisms of preferential adsorption, selective configurational diffusion or molecular sieving.
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Citations
Cited by
Metal–organic framework membranes: from synthesis to separation application
Qiu, S., Xue, M., & Zhu, G. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00159a · Cited by 1,630
Zeolitic imidazolate framework ZIF-7 based molecular sieve membrane for hydrogen separation
Li, Y., Liang, F., Bux, H., Yang, W., & Caro, J. (2010) · Journal of Membrane Science · doi:10.1016/j.memsci.2010.02.074 · Cited by 502
Current Status of Metal–Organic Framework Membranes for Gas Separations: Promises and Challenges
Shah, M., McCarthy, M. C., Sachdeva, S., Lee, A. K., & Jeong, H.-K. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie202038m · Cited by 494
Recent progress of fillers in mixed matrix membranes for CO 2 separation: A review
Vinoba, M., Bhagiyalakshmi, M., Alqaheem, Y., Alomair, A. A., Pérez, A., & Rana, M. S. (2017) · Separation and Purification Technology · doi:10.1016/j.seppur.2017.07.051 · Cited by 438
High-temperature membranes in power generation with CO2 capture
Bredesen, R., Jordal, K., & Bolland, O. (2004) · Chemical Engineering and Processing: Process Intensification · doi:10.1016/j.cep.2003.11.011 · Cited by 386
Metadata
- Authors
- Lin, Y. S., Kumakiri, I., Nair, B. N., & Alsyouri, H.
- Venue
- Separation and Purification Methods
- Publisher
- Informa UK Limited
- Published
- 2002-01-12
- Volume
- 31
- Issue
- 2
- Pages
- 229-379
- ISSN
- 0360-2540 (ISSN-L)
- OpenAlex
- W2071569536
- Cited by
- 276
- References
- 0
- FWCI
- 20.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, Y. S., Kumakiri, I., Nair, B. N., & Alsyouri, H. (2002). MICROPOROUS INORGANIC MEMBRANES. Separation and Purification Methods. https://doi.org/10.1081/spm-120017009
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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