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The chemical potential of radiation

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P Wurfel·1982·Journal of Physics C: Solid State Physics

Abstract

In a thermodynamic treatment electromagnetic radiation of any kind is described. The difference between thermal and non-thermal radiation is accounted for by introducing the chemical potential of photons. Instead of an effective temperature all kinds of radiation have the real temperature of the emitting material. As a result Planck's law for thermal radiation is extended to radiation of any kind. The concept of the chemical potential of radiation is discussed in detail in conjunction with light-emitting diodes, two-level systems, and lasers. It allows the calculation of absorption coefficients, of emission spectra of luminescent materials, and of radiative recombination lifetimes of electrons and holes in semiconductors. Theoretical emission spectra are compared with experimental data on GaAs light-emitting diodes and excellent agreement is obtained.

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Metadata

Authors
Wurfel, P.
Venue
Journal of Physics C: Solid State Physics
Published
1982-06-30
Volume
15
Issue
18
Pages
3967-3985
ISSN
0022-3719 (ISSN-L)
OpenAlex
W1981328983
Cited by
995
References
0
FWCI
1.94
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: The chemical potential of radiation. https://app.cochat.ai/papers/10.1088/0022-3719/15/18/012
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Wurfel, P. (1982). The chemical potential of radiation. Journal of Physics C: Solid State Physics. https://doi.org/10.1088/0022-3719/15/18/012

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