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A study of single-layer and restacked MoS2by X-ray diffraction and X-ray absorption spectroscopy

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Joensen, P, Crozier, E D, Alberding, N, Frindt, R F·1987·Journal of Physics C: Solid State Physics

Abstract

Structural studies of single layers of MoS 2 in aqueous suspension using X-ray diffraction and EXAFS show that single layers differ from bulk single-crystal MoS 2 by having two nearest Mo-Mo distances at 2.8 and 3.8 AA substantially distorted from the bulk value of 3.16AA while the nearest Mo-S distance is essentially unchanged from the bulk value. As an aqueous suspension of single-layer MoS 2 dries, a phase is obtained in which two monolayers of water are present between parallel but rotationally disordered MoS 2 layers, and the bulk Mo-Mo distance starts to reappear. In dry restacked MoS 2 only the bulk Mo-Mo distance is recovered, the same spacing between Mo layers as in single-crystal MoS 2 , is observed and the layers exhibit partial rotational order.

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Metadata

Authors
Joensen, P., Crozier, E. D., Alberding, N., & Frindt, R. F.
Venue
Journal of Physics C: Solid State Physics
Published
1987-09-20
Volume
20
Issue
26
Pages
4043-4053
ISSN
0022-3719 (ISSN-L)
OpenAlex
W2012824934
Cited by
268
References
0
FWCI
0.46
Type
journal article
Language
en
Open access
bronze

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Joensen, P., Crozier, E. D., Alberding, N., & Frindt, R. F. (1987). A study of single-layer and restacked MoS2by X-ray diffraction and X-ray absorption spectroscopy. Journal of Physics C: Solid State Physics. https://doi.org/10.1088/0022-3719/20/26/009

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