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Intrinsic photoconduction and photoemission in polyethylene
Open accessAbstract
Intrinsic photoemission and photoconduction of polyethylene in the photon energy range 7<E<14 eV have been experimentally investigated. Both phenomena are parabolic in E with the same threshold energy E G =8.8 eV. The main features of a model that accounts for the observations are: (a) E G is the intrinsic electron-hole band gap. (b) Strong absorption for 7.6<E<8.8 eV is due to exciton creation. (c) The bottom of the conduction band lies an energy A above the vacuum level, where 0<A<1.2 eV. (d) The photocurrents are due to rapid motion of carriers through a short distance approximately=10 nm along individual polyethylene chains. (e) The carriers subsequently travel through the polyethylene with a very low mobility.
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Citations
Cited by
Molecular modeling of electron traps in polymer insulators: Chemical defects and impurities
Meunier, M., Quirke, N., & Aslanides, A. (2001) · The Journal of Chemical Physics · doi:10.1063/1.1385160 · Cited by 411
First-principle simulations of electronic structure in semicrystalline polyethylene
Moyassari, A., Unge, M., Hedenqvist, M. S., Gedde, U. W., & Nilsson, F. (2017) · The Journal of Chemical Physics · doi:10.1063/1.4983650 · Cited by 52
Metadata
- Authors
- Less, K. J., & Wilson, E. G.
- Venue
- Journal of Physics C: Solid State Physics
- Publisher
- IOP Publishing
- Published
- 1973-10-30
- Volume
- 6
- Issue
- 21
- Pages
- 3110-3120
- ISSN
- 0022-3719 (ISSN-L)
- OpenAlex
- W2125316120
- Cited by
- 161
- References
- 0
- FWCI
- 6.14
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Less, K. J., & Wilson, E. G. (1973). Intrinsic photoconduction and photoemission in polyethylene. Journal of Physics C: Solid State Physics. https://doi.org/10.1088/0022-3719/6/21/014
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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