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Molecular Spectroscopy by Means of ESCA III.Carbon compounds
Open accessAbstract
Carbon 1 s energies are measured by ESCA for a series of aliphatic saturated compounds, carbonyl compounds, and some aromatic compounds. For convenient use in chemical structure analysis the binding energy shifts are correlated with a charge parameter obtained from electronegativity considerations. The shifts are also analyzed in terms of group shifts from which group electronegativities are derived. A comparison is made between the shifts in solid and gaseous samples and it is shown that solid state effects are small for non-ionic compounds. The observed shifts are then compared with results of semi-empirical and ab initio molecular orbital calculations on free molecules. The theoretical calculations are simplified by use of an electrostatic potential model.
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Cited by
Solid-state analysis of eumelanin biopolymers by electron spectroscopy for chemical analysis
Clark, M. B., Gardella, J. A., Schultz, T. M., Patil, D. G., & Salvati, L. (1990) · Analytical Chemistry · doi:10.1021/ac00208a011 · Cited by 115
Siriwardane, R. V., Poston, J. A., Robinson, C., & Simonyi, T. (2011) · Energy & Fuels · doi:10.1021/ef101486m · Cited by 50
Metadata
- Authors
- Gelius, U., Hedén, P. F., Hedman, J., Lindberg, B. J., Manne, R., Nordberg, R., Nordling, C., & Siegbahn, K.
- Venue
- Physica Scripta
- Publisher
- IOP Publishing
- Published
- 1970-07
- Volume
- 2
- Issue
- 1-2
- Pages
- 70-80
- ISSN
- 0031-8949 (ISSN-L)
- 1402-4896
- OpenAlex
- W2036822427
- Cited by
- 609
- References
- 0
- FWCI
- 7.21
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Molecular Spectroscopy by Means of ESCA III.Carbon compounds. https://app.cochat.ai/papers/10.1088/0031-8949/2/1-2/014
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- Gelius, U., Hedén, P. F., Hedman, J., Lindberg, B. J., Manne, R., Nordberg, R., Nordling, C., & Siegbahn, K. (1970). Molecular Spectroscopy by Means of ESCA III.Carbon compounds. Physica Scripta. https://doi.org/10.1088/0031-8949/2/1-2/014
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