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Empirical description of the role of electronegativity in alloy formation
Abstract
Empirical correlations are established, which demonstrate that the heat of formation of metallic binary alloy systems is predominantly determined by the electronegativity difference, the difference in electronic density at the boundary of the atomic cell and the size difference, the third term being absent for compounds. The work function of a metal is recommended as a measure for its electronegativity. The electron density at the cell boundary is shown to be related to the compressibility of the pure metal. The consequences of the energy effects for quantitative descriptions of charge transfer in metallic alloys are discussed extensively.
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Citations
Cited by
On the heat of formation of solid alloys
Miedema, A. R., Boom, R., & De Boer, F. R. (1975) · Journal of the Less Common Metals · doi:10.1016/0022-5088(75)90034-x · Cited by 699
Self-citationReduction of FCCI effects in lanthanide–iron diffusion couples by doping with palladium
Egeland, G. W., Mariani, R. D., Hartmann, T., Porter, D. L., Hayes, S. L., & Kennedy, J. R. (2013) · Journal of Nuclear Materials · doi:10.1016/j.jnucmat.2013.04.060 · Cited by 38
Metadata
- Authors
- Miedema, A. R., Boer, F. R. D., & Chatel, P. F. D.
- Venue
- Journal of Physics F: Metal Physics
- Publisher
- IOP Publishing
- Published
- 1973-08
- Volume
- 3
- Issue
- 8
- Pages
- 1558-1576
- ISSN
- 0305-4608 (ISSN-L)
- OpenAlex
- W2131577694
- Cited by
- 325
- References
- 0
- FWCI
- 31.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Empirical description of the role of electronegativity in alloy formation. https://app.cochat.ai/papers/10.1088/0305-4608/3/8/012
- The paper
- Miedema, A. R., Boer, F. R. D., & Chatel, P. F. D. (1973). Empirical description of the role of electronegativity in alloy formation. Journal of Physics F: Metal Physics. https://doi.org/10.1088/0305-4608/3/8/012
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
